Development of multifunctional ionogels derived from a dynamic deep eutectic solvent

Li, Jintao; Zhang, Mingzu; He, Jinlin; Ni, Peihong

doi:10.1039/d3cc02158k

Chem. Commun.

2023

DOI: 10.1039/d3cc02158k

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Development of multifunctional ionogels derived from a dynamic deep eutectic solvent

Jintao Li

Mingzu Zhang

Jinlin He

et al.

Abstract: Dynamic deep eutectic solvent (DDES) consisting of choline chloride and α-lipoic acid is proposed and applied for thermally-initiated ring-opening polymerization. With the help of dynamic interactions (disulfide, hydrogen and coordination...

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Cited by 8 publications

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References 35 publications

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“…12–16 To date, most of the PDESs are polymerized through vinyl groups and we have recently introduced a cyclic disulfide motif to propose a unique dynamic DES (DDES), which could undergo thermally initiated ring-opening polymerization to construct multifunctional ionogels. 17…”

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confidence: 99%

Unexpected mechanically robust ionic conductive elastomer constructed from an itaconic acid-involved polymerizable DES

Jin,

Li,

Zhang

et al. 2023

Chem. Commun.

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confidence: 99%

Unexpected mechanically robust ionic conductive elastomer constructed from an itaconic acid-involved polymerizable DES

Jin,

Li,

Zhang

et al. 2023

Chem. Commun.

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Lignin Powered Versatile Bioelastomer: A Universal Medium for Smart Photothermal Conversion

Sun,

Dang,

Zhang

et al. 2024

Adv Funct Materials

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Photothermal elastomers are recognized as smart flexible materials that can rapidly and effectively convert light energy into heat energy. However, there has been a lack of adequate focus on tackling the sustainability challenges of photothermal elastomers, particularly in terms of material selection, the integration of complex functionalities, and final disposal. A fully bio‐derived photothermal elastomer (BPTE) produced through a simple and chemical‐free approach is introduced, utilizing alkali lignin, lipoic acid, and phytic acid as bio‐derived feedstocks. The BPTE exhibits an adaptive polymeric network crosslinked by dynamic covalent disulfide bonds and multiple hydrogen bonds, endowing it with dual‐mode photothermal conversion capability, robustness, stretchability, rapidly self‐healing property, hydrophobicity, swelling resistance, self‐adhesion, full recyclability, and degradability. The BPTE is further demonstrated as a next‐generation solution for photothermal generators, light‐driven actuators, photothermal antibacterial dressings, and photothermal fibers. The versatility of BPTE opens avenues for innovative smart devices and systems with significant potential in energy conversion, soft robotics, medical treatment, and smart clothing. With outstanding photothermal performances, full recyclability, and biodegradability, these fully bio‐based elastomers present an attractive prospect for the development of the advanced smart photothermal products.

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Applications of Functional Polymeric Eutectogels

Nicolau,

Mutch,

Thickett

2024

Macromol. Rapid Commun.

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Over the past two decades, deep eutectic solvents (DESs) have captured significant attention as an emergent class of solvents that have unique properties and applications in differing fields of chemistry. One area where DES systems find utility is the design of polymeric gels, often referred to as “eutectogels,” which can be prepared either using a DES to replace a traditional solvent, or where monomers form part of the DES themselves. Due to the extensive network of intramolecular interactions (e.g., hydrogen bonding) and ionic species that exist in DES systems, polymeric eutectogels often possess appealing material properties—high adhesive strength, tuneable viscosity, rapid polymerization kinetics, good conductivity, as well as high strength and flexibility. In addition, non‐covalent crosslinking approaches are possible due to the inherent interactions that exist in these materials. This review considers several key applications of polymeric eutectogels, including organic electronics, wearable sensor technologies, 3D printing resins, adhesives, and a range of various biomedical applications. The design, synthesis, and properties of these eutectogels are discussed, in addition to the advantages of this synthetic approach in comparison to traditional gel design. Perspectives on the future directions of this field are also highlighted.

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Development of multifunctional ionogels derived from a dynamic deep eutectic solvent

Abstract: Dynamic deep eutectic solvent (DDES) consisting of choline chloride and α-lipoic acid is proposed and applied for thermally-initiated ring-opening polymerization. With the help of dynamic interactions (disulfide, hydrogen and coordination...

Cited by 8 publications

References 35 publications

Unexpected mechanically robust ionic conductive elastomer constructed from an itaconic acid-involved polymerizable DES

Unexpected mechanically robust ionic conductive elastomer constructed from an itaconic acid-involved polymerizable DES

Lignin Powered Versatile Bioelastomer: A Universal Medium for Smart Photothermal Conversion

Applications of Functional Polymeric Eutectogels

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