Development of multifunctional cotton fabrics using difunctional polysiloxanes

Przybylak, Marcin; Maciejewski, Hieronim; Dudkiewicz, Agnieszka; Walentowska, J.; Foksowicz-Flaczyk, Joanna

doi:10.1007/s10570-017-1621-2

Cited by 24 publications

(8 citation statements)

References 36 publications

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“…Multifunctional cotton fabric can be made by chemical treatments performed by the following techniques: (1) successive treatment (layer-by-layer); (2) classic treatment, in a single stage (single-layer) [ 1 ]. Using the layer-by-layer technique, the cellulosic materials were functionalized in two or more stages, leading to a wide range of effects, as follows: Wrinkle-free, antibacterial, flame retardant and antioxidant properties on linen fabrics due to a finishing with chitosan-citric acid and phytic acid-thiourea [ 2 ]; Wrinkle-free, antibacterial, flame retardant, UV protection and antioxidant properties using layer-by-layer finishing with chitosan, sodium lignin sulphonate and boric acid [ 3 ]; Biocidal and hydrophobic properties when the cotton fabrics were modified with difunctional polysiloxanes [ 4 ]; Water repellence, flame retardance and antibacterial properties through deposition of three-dimensional tetrakis (hydroxymethyl) phosphonium chloride-urea polymer coating [ 5 ]; Crease resistance in addition with the antimicrobial effects on knitted fabric using dimethylol dihydroxy ethylene urea (DMDHEU) and titanium dioxide (TiO 2 ) [ 6 ]. …”

Section: Introductionmentioning

confidence: 99%

“…Biocidal and hydrophobic properties when the cotton fabrics were modified with difunctional polysiloxanes [ 4 ];…”

Section: Introductionmentioning

confidence: 99%

“…All these studies indicate that the chemical component of the treatment agents and especially their reactivities determine the diversity and number of effects obtained during the multifunctional finishing of cotton. Conferring antibacterial effects simultaneously with various other effects was possible by using classic/ecofriendly finishing compounds in the presence/absence of some biocides (TiO 2 , silver ions or nanoparticles, zinc oxide nanoparticles) [ 2 , 3 , 4 , 5 , 6 , 8 , 9 , 10 , 11 , 13 ]. The combination of wrinkle-proofing and hydrophilicity effects on cotton is extremely difficult to achieve even when using compounds with increased reactivity and functionality (such as glyoxal and MCT-β-CD), commonly used in wrinkle-proofing treatments.…”

Section: Introductionmentioning

confidence: 99%

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Multifunctional Finishing of Cotton with Compounds Derived from MCT-β-CD and Quantification of Effects Using MLR Statistical Analysis

2021

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Multifunctionalization of cotton using a single product has not been made until now. Such a product was synthesized using compounds with multiple functions (glyoxal, ethylenediamine (ED) and monochlorotriazinyl-β–cyclodextrin (MCT-β-CD)), under different mass ratios. Obtaining this multifunctional derivative has been confirmed by spectroscopic analyses (1H-NMR and FTIR) and a scanning electron microscope (SEM). Treatment of cotton with the MCT-β-CD derivative (D-CD) has been realized with the pad dry-cure technology. The presence of this multifunctional derivative on cotton was highlighted with spectroscopic (FTIR, EDAX, XRD) and thermoanalytical (DSC) methods. The objective of treating cotton with D-CD was to achieve four simultaneous effects: large wrinkle recovery angle (WRA), hydrophilicity, antibacterial capacity and a good breaking resistance. This objective has been achieved, so the garments that will be manufactured with such multifunctional cotton will be more comfortable. The efficiency of treatments with D-CD was marked out by multiple linear regression (MLR) and certain quality indices. Using MLR, the behavior of the treated cotton was mathematically modeled and the stationary/optimal points corresponding to each effect were calculated. Quality indices have been calculated and all final samples had values higher than 1, which confirmed the positive effects exerted by D-CDs on cotton.

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Section: Introductionmentioning

confidence: 99%

“…Biocidal and hydrophobic properties when the cotton fabrics were modified with difunctional polysiloxanes [ 4 ];…”

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Multifunctional Finishing of Cotton with Compounds Derived from MCT-β-CD and Quantification of Effects Using MLR Statistical Analysis

2021

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“…Cotton was initially decorated with single functionality including N-halamines (Nchloramines and N-bromamines) (Cheng X et al, 2015;Luo G et al, 2017;Zhang S et al, 2019), antibiotics (Liu X Y et al, 2019;Qu W et al, 2019), metals and metal oxides (El-Rafie M et al, 2014;Ibrahim M M et al, 2019;Xu Q et al, 2018), and cationic salts (quaternary ammonia salts and pyridinium ions, etc.) (Przybylak M et al, 2018;Zhang S et al, 2018b). N-halamines and cationic salts have stood out due to their low cost, broad-spectrum efficacy, and abound types.…”

Section: Introductionmentioning

confidence: 99%

Engineering of super bactericidal cotton using pyridinium/di-N-chloramine siloxane with intensified synergism

Chen

Wang

et al. 2021

Cellulose

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Tuning the ratio of complementary biocidal groups in a composite unit is proved to be a tactic to better minimize their weaknesses to realize higher synergism. A silane monomer, 6-(pyridin-4-yl)-3-(3-(trimethoxysilyl)propyl)-1,3,5-triazinane-2,4dione, with biocidal precursors of one pyridinium and two N-chloramine sites was synthesized, hydrolyzed and dehydrocondensed on cotton cellulose. Specially, isonicotinaldehyde was ammonolyzed with biuret to produce 6-(pyridin-4-yl)-1,3,5triazinane-2,4-dione that subsequently reacted with (γ-chloropropyl)trimethoxysilane to synthesize the silane monomer through nucleophilic substitution. The modifier on cotton was quaternized and chlorinated to transform the one pyridine and two amide N−H structures in each unit of the silicone to pyridinium and N-chloramine counterparts.The cationic pyridinium increases the hydrophilicity of the unit and electrically draws anionic bacteria to its two adjacent highly fatal N-chloramine sites, achieving a faster contact-killing rate than not only monofunctionality but also basic synergistic

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“…Biocidal modification of PE surface is necessary to acquire even further applications, especially in biomaterials and health‐care industries . Compared with reactive materials such as cellulose that has hydroxyl groups to provide versatile linkages with other moieties through reactions including substitution, condensation, and esterification, direct modification of inert PE via currently used physical or chemical methods is hard due to its low surface tension and the lack of reactivity.…”

Section: Introductionmentioning

confidence: 99%

Preparation of silicone containing 2,2,6,6‐tetramethyl‐4‐piperidinol‐basedN‐chloramine for antibacterial polyethylene via interpenetration in supercritical carbon dioxide

Chen

Wang

Zhang

et al. 2019

J of Applied Polymer Sci

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Functionalization of polyethylene (PE) with powerful biocides through a friendly and efficient procedure is necessary to obtain extended applications. A novel CO 2 -philic 2,2,6,6-tetramethyl-4-piperidinol (TMP)-based N-chloramine silicone was synthesized via Pt-catalyzed silane alcoholysis between the Si H of poly(methylhydrosiloxane) and O H of TMP and followed by chlorination of amine N H originating from TMP to N Cl. The TMP-based N-chloramine silicone was interpenetrated into PE using supercritical carbon dioxide (scCO 2 ) as working solvent. It was shown that the thickness of the TMP-based N-chloramine silicone layer on PE can be easily controlled by the interpenetration pressure, reaching a maximum value of 70 nm at 28 mp. The synthetic procedures and the interpenetration results were characterized by Fourier transform infrared, scanning electron microscopy, and X-ray photoelectron spectroscopy. In contrast with pristine PE that did not show biocidal ability, the TMP-based N-chloramine silicone modified PE imparted powerful antibacterial abilities, exerting total kills of both Staphylococcus aureus and Escherichia coli of~10 7 cfu mL −1 in 30 min. The biocidal functionality was durable toward washings, storage, and ultraviolet exposure and the recoverability of lost chlorines was good. The interpenetration in scCO 2 tactic provides an environmentally friendly and universal approach to functionalize inert substrates due to no needs of harmful solvent and chemical linkages with biocides.The mainly used biocidal compounds include N-halamines (Nchloramines and N-bromamines), 6-17 quaternary ammonia salts, 18-25 and heavy-metal ions. 26,27 N-halamines are famous and widely used biocidal groups since they are broad spectrum, rechargeable, very stable, and highly efficient. 28,29 Their antibacterial capacity originates from the positively charged halamines (+1) that function as oxidizing agents to oxidize or destruct enzymatic and/or metabolic activities of microorganisms. N-halamines are formed by halogenation of imide/amide/amine N H to N Cl or N Br. The corresponding structures are called imide/amide/amine N-halamines with a stability order of imide < amide < amine structures. 30 As an amine N-halamine precursor, 2,2,6,6-tetramethyl-4-piperidinol (TMP) is stable due to its hindered structure, 31 resistant to photodegradation due to its regular function as ultraviolet (UV) stabilizer, 32 and lack Additional Supporting Information may be found in the online version of this article.

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Development of multifunctional cotton fabrics using difunctional polysiloxanes

Cited by 24 publications

References 36 publications

Multifunctional Finishing of Cotton with Compounds Derived from MCT-β-CD and Quantification of Effects Using MLR Statistical Analysis

Multifunctional Finishing of Cotton with Compounds Derived from MCT-β-CD and Quantification of Effects Using MLR Statistical Analysis

Engineering of super bactericidal cotton using pyridinium/di-N-chloramine siloxane with intensified synergism

Preparation of silicone containing 2,2,6,6‐tetramethyl‐4‐piperidinol‐basedN‐chloramine for antibacterial polyethylene via interpenetration in supercritical carbon dioxide

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