2014
DOI: 10.1149/2.023406jss
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Development of an Equation to Model Electrical Conductivity of Polymer-Based Carbon Nanocomposites

Abstract: A statistical-thermodynamic formula based on a new approach has been developed to predict electrical conductivity of polymer-based carbon composites, used for bipolar plate of proton exchange membrane fuel cells. In the model, based on the percolation threshold phenomenon, the relationship between electrical conductivity of composite versus the filler volume fraction is represented as sigmoidal distribution. Moreover, four variables, including filler electrical conductivity, filler aspect ratio, filler roundne… Show more

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Cited by 83 publications
(61 citation statements)
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“…In general, the Fourier model is very similar to the sigmoidal model [16] by both the "S"-like shape, which qualitatively corresponds to a typical percolation curve, and the influence of most parameters on the value of the total electrical conductivity of the system. The main variable parameter of the Fourier model is the parameter b, which changes the shape of the curve.…”
Section: The Fourier Modelmentioning
confidence: 78%
“…In general, the Fourier model is very similar to the sigmoidal model [16] by both the "S"-like shape, which qualitatively corresponds to a typical percolation curve, and the influence of most parameters on the value of the total electrical conductivity of the system. The main variable parameter of the Fourier model is the parameter b, which changes the shape of the curve.…”
Section: The Fourier Modelmentioning
confidence: 78%
“…where A 1 and A 2 represent limiting conductivity values, B is the slope and the rest of parameters preserves the meaning mentioned previously. This model has been validated for both micro and nanofillers . The fitting procedure utilizing the experimental data (Figure ) yielded percolation threshold at approximately 19 % wt.…”
Section: Resultsmentioning
confidence: 96%
“…When the amount of the electronic filler loaded in the composite exceeds the percolation threshold (bottom-line for the percolation network formation), conductive pathways for carrier transport are generated in the composite. [52][53][54] As such, higher filler contents above the percolation thresholds lead to the dramatic increase in conductivity of the percolation network. When the filler of the too much amount is loaded, however, the crosslinking density of the elastomer network becomes lowered, causing an overall degradation of the mechanical performance of the elastomers such as strain durability and/or mechanical toughness.…”
Section: Electronic Fillersmentioning
confidence: 99%