Development of an accelerated test for Internal Sulfate Attack study

Abstract

Abstract. Internal Sulfate Attack (ISA) is a pathology that occurs under certain conditions in concrete having undergone heating above 70 °C at early age (through heating in pre-casting industry or due to hydration in large concrete parts). This reaction deemed very slow, numerous methods to speed up reactions leading to delayed ettringite formation have been developed. These methods are all based on the material damage. Another type of test is currently under development. It is based on rehabilitation techniques such as electrochemical chloride extraction (ECE) in order to accelerate the leaching of alkalis that could be one of the triggers of the pathology. The study presented in this paper focused on concrete specimens prepared from cement (CEM I 52.5 N) enriched with Na2SO4. These concretes have undergone a heat treatment typical of those used in precast plants (up to 24 hours with a maximum temperature of 80 °C). Various paths were explored for the development of the accelerated test. The first results showed that it was necessary to use a removable titanium anode ruthenium anode instead of stainless steel embedded in the concrete. Then tests with de-ionized water as the solute to the cathode did not accelerate the onset of expansions. The experiment has been modified and potassium carbonate was added to the solution. This modification didn't show any significant improvement, and other experiments are being carried out to explain this result.

Reação Sulfática Interna (RSI) como degradação de matriz cimentícia: comportamento de pastas dosadas com diferentes teores de contaminação por sulfato

“…Specific studies in this area started to appear in the beginning of the 80's in Europe and North America (KHELIL, 2014). Degradation mechanisms in concrete structures, having contaminated aggregate, are initially caused by the phenomenon of oxidation of the mineral sulfide in the presence of humidity.…”