Development of all-solid lithium-ion battery using Li-ion conducting glass-ceramics

Inda, Yasushi; Katoh, Takashi; Baba, Mamoru

doi:10.1016/j.jpowsour.2007.06.234

Cited by 81 publications

(47 citation statements)

References 2 publications

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“…According to Equation (10) ) was also based on the mass of Cu 2+ generated during the charge process (18.96 mg). This result indicates that the electrochemical dissolution-deposition of Cu-cathode in aqueous solution is reversible at approximately 100 % efficiency.…”

Section: Li-metal Rechargeable Batteriesmentioning

confidence: 99%

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The Development of a New Type of Rechargeable Batteries Based on Hybrid Electrolytes

Zhou

Wang

et al. 2010

ChemSusChem

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Lithium ion batteries (LIBs), which have the highest energy density among all currently available rechargeable batteries, have recently been considered for use in hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and pure electric vehicles (PEV). A major challenge in this effort is to increase the energy density of LIBs to satisfy the industrial needs of HEVs, PHEVs, and PEVs. Recently, new types of lithium-air and lithium-copper batteries that employ hybrid electrolytes have attracted significant attention; these batteries are expected to succeed lithium ion batteries as next-generation power sources. Herein, we review the concept of hybrid electrolytes, as well as their advantages and disadvantages. In addition, we examine new battery types that use hybrid electrolytes.

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Section: Li-metal Rechargeable Batteriesmentioning

confidence: 99%

“…Some solid-state LISICON electrolytes are also difficult to use within ranges to as low as 0.0 V vs. Li/Li + because the metal oxide in the LISICON may be reduced. [8,10] For these reasons and based upon recent research progress made within our group, [11][12][13][14] we seek to address these issues by introducing a hybrid electrolyte.…”

Section: Introductionmentioning

confidence: 99%

The Development of a New Type of Rechargeable Batteries Based on Hybrid Electrolytes

Zhou

Wang

et al. 2010

ChemSusChem

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“…The safety issues related to the use of conventional combustible organic electrolytes are of great concern in large batteries for vehicle or grid applications. 20 Therefore, the development of a composite electrolyte with strongly beneficial physical and electrochemical properties and low solid-solid interface resistance remains a challenge. For the solid electrolytes, solid-phase materials such as Na-ion conductive ceramics, polymers, or ceramic and polymer composites have been considered as potential rechargeable battery electrolytes.…”

Section: Introductionmentioning

confidence: 99%

A hybrid solid electrolyte for flexible solid-state sodium batteries

Kim

Lim

Kim

et al. 2015

Energy Environ. Sci.

216

156

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Development of Na-ion battery electrolyte with high-performance electrochemical properties and high safety is still challenging to achieve. In this study, we report on a NASICON (Na 3 Zr 2 Si 2 PO 12 )-based composite hybrid solid electrolyte (HSE) designed for use in a high safety solid-state sodium battery for the first time. The composite HSE design yields the required solid-state electrolyte properties for this application, including high ionic conductivity, a wide electrochemical window, and high thermal stability.The solid-state batteries of half-cell type exhibit an initial discharge capacity of 330 and 131 mA h g À1 for a hard carbon anode and a NaFePO 4 cathode at a 0.2C-rate of room temperature, respectively.Moreover, a pouch-type flexible solid-state full-cell comprising hard carbon/HSE/NaFePO 4 exhibits a highly reversible electrochemical reaction, high specific capacity, and a good, stable cycle life with high flexibility. Broader contextThe considerable interest in Na-ion batteries has continued to increase as a result of their applicability to large-scale energy storage systems, and also because of the high abundance and uniform worldwide distribution of Na and its corresponding low cost compared to Li. However, safety issues related to the use of conventional combustible organic electrolytes in large-scale batteries for vehicle or grid applications are of great concern. It is anticipated that such safety issues can be fully addressed through the use of non-flammable solid electrolytes in solid-state batteries. However, the application of solid ceramic and polymer electrolytes in batteries has led to poor electrochemical performance, which is primarily due to the resultant high solid-solid interface resistance. Thus, a new electrolyte strategy is urgently required in order to overcome this problem. In this work, a NASICON (Na 3 Zr 2 Si 2 PO 12 ) ceramic-based hybrid solid electrolyte (HSE) is proposed and shown to exhibit high electrochemical performances as a result of its decreased interface resistance, high thermal stability, and high electrochemical stability. Using the HSE, a flexible pouch-type full cell of hard carbon/HSE/NaFePO 4 is assembled for the first time, exhibiting good and stable cycle performance with a high capacity. † Electronic supplementary information (ESI) available: XRD, FT-IR, SEM-EDX, DSC, FT-Raman, Arrhenius plots, bond length of CF 3 SO 3 , shrinkage test, chargedischarge curves, photographs of a flexible solid-state Na battery, short-term cycling of flexible solid-state batteries with conducting and non-conducting ceramic. See

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“…Recently, the NASICON-type Li-ion conducting electrolyte consisted of Li 2 O-Al 2 O 3 -SiO 2 -P 2 O 5 -TiO 2 has received great attention because of its high Li-ion conductivity of 10 −4 ∼ 10 −3 S cm −1 at room temperature [1,2]. Birke et al [3] successfully cycled the all-solid-state Li 4 Ti 5 O 12 /Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 /LiMn 2 O 4 cell which exhibited a charge-discharge plateau at around 2.5 V. Inda et al [4] also reported the all-solid-state Li 4 Ti 5 O 12 /composite electrolyte/LiCoO 2 cell which showed good charge-discharge performance. The composite electrolyte was composed of NASICONtype glass ceramics and ployethyleneoxide (PEO)-based polymer electrolyte.…”

Section: Introductionmentioning

confidence: 99%

Li-ion transport in all-solid-state lithium batteries with LiCoO2 using NASICON-type glass ceramic electrolytes

Xie

Imanishi

Zhang

et al. 2009

Journal of Power Sources

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Development of all-solid lithium-ion battery using Li-ion conducting glass-ceramics

Cited by 81 publications

References 2 publications

The Development of a New Type of Rechargeable Batteries Based on Hybrid Electrolytes

The Development of a New Type of Rechargeable Batteries Based on Hybrid Electrolytes

A hybrid solid electrolyte for flexible solid-state sodium batteries

Li-ion transport in all-solid-state lithium batteries with LiCoO2 using NASICON-type glass ceramic electrolytes

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