An inorganic hexalanthanide-oxo cluster encapsulated antimotungstate, K2Na3H43[Nd6(OH)6(H2O)6(B-α-SbW9O33)4]2·67H2O (1),has been successfully synthesized by a facile one-step hydrothermal reaction method.The tetrahedron-shaped two-shell {Nd6(OH)6(H2O)6(B-α-SbW9O33)4}(1a) polyanion is composed of a novel pure lanthanide-oxo {Nd6(μ3-OH)6(H2O)6}...