Development and validation of HPLC–ICP-MS method for the determination inorganic Cr, As and Sb speciation forms and its application for Pławniowice reservoir (Poland) water and bottom sediments variability study

Speciation of Antimony(III) and Antimony(V) in Bottled Water by Hydride Generation-Inductively Coupled Plasma Optical Emission Spectrometry

“…The limits of detection are lower in than the literature values involving ICP OES (Feng et al 1999;Li, Hu, and Jiang 2006;Menegario et al 2006). Only HPLC-ICP-MS (Ge and Wei 2013;Jablońska-Czapla et al 2014) and HG-AFS (Fuentes et al 2003) provided lower limits of detection compared to this work. No preconcentration procedure was used in this study, even though the limits of detection were similar or lower in comparison with other methods using preconcentration (Fan 2005;Li, Hu, and Jiang 2006;Menegario et al 2006;Zheng et al 2006;Samadi-Maybodi and Rezaei 2012).…”

“…Various analytical methods have been used for the determination and speciation of the inorganic antimony, such as high-performance liquid chromatography with inductively coupled plasma-mass spectrometry (HPLC-ICP-MS) (Smichowski et al 1995;Zheng, Iijima, and Furuta 2001;Ge and Wei 2013;Jablońska-Czapla et al 2014), atomic absorption spectrometry (AAS) (Fan 2005;Zheng et al 2006;Flores et al 2007;Matusiewicz and Krawczyk 2008;Ferreira et al 2011), atomic fluorescence spectrometry (Deng, Chen, and Belzile 2001), inductively coupled plasma optical emission spectrometry (ICP OES) (Menegario et al 2006;Menegario et al 2008;Depoi and Pozebon 2012), and inductively coupled plasma-mass spectrometry (ICP-MS) (Westerhoff et al 2008). Spectrometric techniques have been used for the speciation of Sb (Feng et al 1999;Menegario et al 2006;Zheng et al 2006;Flores et al 2007;Menegario et al 2008 Ferreira et al 2011) using hydride generation (HG) systems with adequate sensitivity.…”

“…The determination and speciation of antimony is well established typically involving HPLC-ICP-MS (Zheng, Iijima, and Furuta 2001;Ge and Wei 2013;Jablońska-Czapla et al 2014) that allows separation and the identification with low limits of detection. However, for hydride generation methods such as HG-ICP OES (Menegario et al 2006;Depoi and Pozebon 2012), usually a preconcentration procedure is necessary to achieve low limits of detection.…”

Variability in different antimony, arsenic and chromium species in waters and bottom sediments of three water reservoirs in Upper Silesia (Poland): a comparative study

“…The second part offers a comparative study of the three above-mentioned reservoirs, which were investigated in 2012-2014. The detailed results of the research into the Pławniowice water and bottom sediments conducted in 2012 were discussed in the study [24]. The same work presented the details of the analytical methodologies developed and validated for determining particular analytes in the supernatant water and sediments.…”

Magnetic solid phase extraction for the determination of trace antimony species in water by inductively coupled plasma mass spectrometry

“…Up till now, the chromatographic techniques including liquid chromatography (LC) [15,16], gas chromatography (GC), [17] and capillary electrophoresis (CE) [18], and non-chromatographic techniques including solid phase extraction (SPE) [19][20][21][22], liquid-liquid extraction (LLE) [23] and cloud point extraction (CPE) [24] have been exploited for the separation of antimony species, followed by element-specific determination. Among these techniques, SPE features simple device and can enrich the species of interest, making it desirable procedure for speciation analysis [25][26][27].…”