Development and Characterization of Thermoresponsive Smart Self-Adaptive Chitosan-Based Polymer for Wellbore Plugging

Abstract

To meet the escalating demand for oil and gas exploration in microporous reservoirs, it has become increasingly crucial to develop high-performance plugging materials. Through free radical grafting polymerization technology, a carboxymethyl chitosan grafted poly (oligoethylene glycol) methyl ether methyl methacrylate acrylic acid copolymer (CCMMA) was successfully synthesized. The resulting CCMMA exhibited thermoresponsive self-assembling behavior. When the temperature was above its lower critical solution temperature (LCST), the nanomicelles began to aggregate, forming mesoporous aggregated structures. Additionally, the electrostatic repulsion of AA chains increased the value of LCST. By precisely adjusting the content of AA, the LCST of CCMMA could be raised from 84.7 to 122.9 °C. The rheology and filtration experiments revealed that when the temperature surpassed the switching point, CCMMA exhibited a noteworthy plugging effect on low-permeability cores. Furthermore, it could be partially released as the temperature decreased, exhibiting temperature-switchable and self-adaptive plugging properties. Meanwhile, CCMMA aggregates retained their reversibility, along with thermal thickening behavior in the pores. However, more detailed experiments and analysis are needed to validate these claims, such as a comprehensive study of the CCMMA copolymer’s physical properties, its interaction with the reservoir environment, and its performance under various conditions. Additionally, further studies are required to optimize its synthesis process and improve its efficiency as a plugging material for oil and gas recovery in microporous reservoirs.