Detonation performance of nitroaromatic decorated carbon nanotubes

Sarvarian, Susan; Zamani, Mehdi

doi:10.1007/s11224-020-01703-9

Cited by 8 publications

(1 citation statement)

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“…Based on these results, thermal correction to enthalpy (Δ H °) is negative. The value of thermal correction to Gibbs free energy (Δ G °) for all configurations is positive, which indicates that the mentioned reaction cannot be occurred spontaneously …”

Section: Results and Discussionmentioning

confidence: 99%

Functionalization of Magnetic UiO-66-NH₂ with a Chiral Cu(l-proline)₂ Complex as a Hybrid Asymmetric Catalyst for CO₂ Conversion into Cyclic Carbonates

Rezayati,

Morsali

2024

Inorg. Chem.

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Cu(L-proline) 2 ] via multifunctionalization strategies was designed and synthesized. One simple approach to chiralize an achiral MOF-structure that cannot be directly chiralized using a chiral secondary agent like 4-hydroxy-L-proline. Therefore, this chiral catalyst was synthesized with a simple and multistep method. Accordingly, Fe 3 O 4 @SiO 2 @UiO-66-NH 2 has been synthesized via Fe 3 O 4 modification with tetraethyl orthosilicate and subsequently with ZrCl 4 and 2-aminoterephthalic acid. The presence of the silica layer helps to stabilize the Fe 3 O 4 core, while the bonding between Zr 4+ and the −OH groups in the silica layer promotes the development of Zr-MOFs on the Fe 3 O 4 surface, and then the surfaces of the synthesized magnetic MOFs composite are functionalized with 1,2-dichloroethane and Cu(II) complex with 4-hydroxy-L-proline, [Cu(L-proline) 2 ] to afford the magnetically chiral nanocatalyst. Multiple techniques were employed to characterize this magnetically chiral nanocatalyst such as Fourier transform infrared (FT-IR), X-ray photoelectron spectroscopy (XPS), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectrometry (EDX), powder X-ray diffraction (PXRD), circular dichroism (CD), inductively coupled plasma (ICP), thermogravimetric analysis (TGA), vibrating-sample magnetometry (VSM), and Brunauer−Emmett−Teller (BET) analyses. Moreover, a magnetically chiral nanocatalyst shows the asymmetric CO 2 fixation reaction under solvent-free conditions at 80 °C and in ethanol under reflux conditions with up to 99 and 98% ee, respectively. Furthermore, the reaction mechanism was illustrated concerning the total energy of the reactant, intermediates and product, and the structural parameters were analyzed.

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Section: Results and Discussionmentioning

confidence: 99%

Functionalization of Magnetic UiO-66-NH₂ with a Chiral Cu(l-proline)₂ Complex as a Hybrid Asymmetric Catalyst for CO₂ Conversion into Cyclic Carbonates

Rezayati,

Morsali

2024

Inorg. Chem.

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Electronic structure and spectroscopy of C60 nitroaryl radical adducts

Moghadam

Zamani

2021

Computational and Theoretical Chemistry

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A novel Cu(II) nanoparticles anchored on cyanuric chloride-attached magnetic nanocatalyst: A highly stable, recyclable and efficient nanocatalyst for the synthesis of chromene derivatives

Kalantari,

Rezayati,

Manafi Moghadam

et al. 2024

Inorganic Chemistry Communications

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Detonation performance of nitroaromatic decorated carbon nanotubes

Cited by 8 publications

References 50 publications

Functionalization of Magnetic UiO-66-NH₂ with a Chiral Cu(l-proline)₂ Complex as a Hybrid Asymmetric Catalyst for CO₂ Conversion into Cyclic Carbonates

Functionalization of Magnetic UiO-66-NH₂ with a Chiral Cu(l-proline)₂ Complex as a Hybrid Asymmetric Catalyst for CO₂ Conversion into Cyclic Carbonates

Electronic structure and spectroscopy of C60 nitroaryl radical adducts

A novel Cu(II) nanoparticles anchored on cyanuric chloride-attached magnetic nanocatalyst: A highly stable, recyclable and efficient nanocatalyst for the synthesis of chromene derivatives

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Detonation performance of nitroaromatic decorated carbon nanotubes

Cited by 8 publications

References 50 publications

Functionalization of Magnetic UiO-66-NH2 with a Chiral Cu(l-proline)2 Complex as a Hybrid Asymmetric Catalyst for CO2 Conversion into Cyclic Carbonates

Functionalization of Magnetic UiO-66-NH2 with a Chiral Cu(l-proline)2 Complex as a Hybrid Asymmetric Catalyst for CO2 Conversion into Cyclic Carbonates

Electronic structure and spectroscopy of C60 nitroaryl radical adducts

A novel Cu(II) nanoparticles anchored on cyanuric chloride-attached magnetic nanocatalyst: A highly stable, recyclable and efficient nanocatalyst for the synthesis of chromene derivatives

Contact Info

Product

Resources

About

Functionalization of Magnetic UiO-66-NH₂ with a Chiral Cu(l-proline)₂ Complex as a Hybrid Asymmetric Catalyst for CO₂ Conversion into Cyclic Carbonates

Functionalization of Magnetic UiO-66-NH₂ with a Chiral Cu(l-proline)₂ Complex as a Hybrid Asymmetric Catalyst for CO₂ Conversion into Cyclic Carbonates