2012
DOI: 10.1146/annurev-physchem-032210-103346
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Deterministic Assembly of Functional Nanostructures Using Nonuniform Electric Fields

Abstract: The force induced on anisotropic nanoparticles in a nonuniform electric field can be used to attract, orient, and position the nanoparticles with respect to microelectrodes on a surface. For polarizable nanomaterials, such as nanowires, carbon nanotubes, or graphene sheets suspended in solvent, this dielectrophoretic force results in movement to regions of highest electric field strength. This review discusses the origin of this force, its production by different microelectrode designs, and its use for nanomat… Show more

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Cited by 53 publications
(67 citation statements)
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“…It allows for dielectrophoretic assembly at a low-enough frequency, where the dielectrophoretic force is independent of nanotube permittivity so that both metallic and semiconducting nanotubes can be deposited simultaneously 30 . It also reduces the solution conductivity (s sol ) and therefore increases the magnitude of the dielectrophoretic force on the nanotubes, which is proportional to (s tube À s sol )/s sol , where s tube is the conductivity of carbon nanotubes 22 . A function generator supplies the alternating voltage signal (sinusoid with a peak-to-peak voltage of 5 V and a frequency of 400 kHz) to the electrodes for 4 min, and a final wash with deionized water completes the assembly process.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…It allows for dielectrophoretic assembly at a low-enough frequency, where the dielectrophoretic force is independent of nanotube permittivity so that both metallic and semiconducting nanotubes can be deposited simultaneously 30 . It also reduces the solution conductivity (s sol ) and therefore increases the magnitude of the dielectrophoretic force on the nanotubes, which is proportional to (s tube À s sol )/s sol , where s tube is the conductivity of carbon nanotubes 22 . A function generator supplies the alternating voltage signal (sinusoid with a peak-to-peak voltage of 5 V and a frequency of 400 kHz) to the electrodes for 4 min, and a final wash with deionized water completes the assembly process.…”
Section: Resultsmentioning
confidence: 99%
“…It utilizes an inhomogeneous electric field, typically formed between a pair of planar microelectrodes, to manipulate the placement of nanomaterials via interaction with their induced dipole moment 22 . However, limited success has been achieved with carbon nanotubes.…”
mentioning
confidence: 99%
“…Therefore, the DEP force needs to overcome those effects in order to effectively perform deposition. Additionally, the DEP force will always depend on the ratio between the electrodes gap and NW lengths (Figure 2b), as this ratio influences the electric field lines density covering the NW and thus the applied torque [35]. The DEP force is maximized (attraction force, see in Figure 2b) for a ratio of around 0.8, since the electric field gradient and strength effects are the largest for this ratio [36].…”
Section: Dep Theorymentioning
confidence: 99%
“…For a smaller gap, the DEP force decreases because, despite that the electric field applied at the gap centre remains constant, it is reduced around the entire NW length. On the other hand, for a larger gap, the DEP force also decreases, simply because the electric field around the NW is less intense [5,35,36]. In this work, for NiNWs length of (4 ± 1) µm, we used a gap length of (2.5 ± 0.3) µm, yielding a ratio of (0.6 ± 0.2), which is near the maximum DEP force condition.…”
Section: Dep Theorymentioning
confidence: 99%
“…The integration of these dissimilar materials will require novel Si fab compatible fabrication techniques. One approach showing significant promise is the electrostatic assisted self-assembly technique being developed at Penn State [37]. The approach is being used to integrate 'chemically functionalized' metallic and semiconducting nanowires and 'chiplets' onto Si CMOS wafers to create chemical and biological sensors.…”
Section: Future Prospectsmentioning
confidence: 99%