Determining the geochemical fingerprint of the lead fallout from the Notre-Dame de Paris fire: Lessons for a better discrimination of chemical signatures

Briard, Justine; Ayrault, Sophie; Roy‐Barman, Matthieu; Bordier, Louise; L'Héritier, Maxime; Azema, Aurélia; Syvilay, Delphine; Baron, Sandrine

doi:10.1016/j.scitotenv.2022.160676

Cited by 5 publications

(19 citation statements)

References 58 publications

(83 reference statements)

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“…Uncertainties from our measurements are smaller than the symbol sizes. (A) 206 Pb/ 207 Pb vs 208 Pb/ 206 Pb diagram: Pb isotopes measured by Glorennec et al in Notre-Dame dusts and melted Pb are shown in purple (2 “outliers” are not figured); Notre-Dame indoor fire dusts are from Briard et al; background Pb isotope chronological evolution of the French atmosphere is based on dated peat layers from eastern and south France, Belgium and Swiss Jura (original data Hansson et al, Forel et al, Shotyk et al, Allan et al). The inner panel is a zoom on the filter data and the data from Briard et al (B) 206 Pb/ 204 Pb vs 208 Pb/ 204 Pb diagram with indoor dust data from Briard et al…”

Section: Resultsmentioning

confidence: 99%

“…The first study to look at the isotopic signature of lead was based on single collector mass spectrometry measurements which did not allow for a very accurate measurement of lead-204 . A second, more recent study succeeded in determining the isotopic signature of lead with a more precise selection of dusts inside the building and a MC-ICP-MS measurement protocol strictly identical to ours. This selection of indoor dust seems appropriate since the isotopic signature of lead in the plume is in particular similar to that measured in sample “ND140619-06 (I)”, made of fine dust collected on the wood of the Notre-Dame organ.…”

Section: Resultsmentioning

confidence: 99%

“…The isotopic signature at the site is variable depending on the lead objects or molten or emitted lead collected at the site. The first study to look at the isotopic signature of lead was based on single collector mass spectrometry measurements which did not allow for a very accurate measurement of lead- 19 background Pb isotope chronological evolution of the French atmosphere is based on dated peat layers from eastern and south France, Belgium and Swiss Jura (original data Hansson et al, 21 Forel et al, 22 Shotyk et al, 23 Allan et al 24 ). The inner panel is a zoom on the filter data and the data from 204.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

“…This selection of indoor dust seems appropriate since the isotopic signature of lead in the plume is in particular similar to that measured in sample "ND140619-06 (I)", made of fine dust collected on the wood of the Notre-Dame organ. Briard et al 19 showed that the isotopic signature was distinct from the legacy lead stored in different compartments in Paris. However, put in a more general spatial and historic context, the signature of the Notre-Dame fire plume is relatively indistinguishable from the recent isotopic signature trend of the air in France as determined by atmospheric environmental archives such as Sphagnum bogs (Figure 3).…”

Section: ■ Results and Discussionmentioning

confidence: 99%

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Lead from Notre-Dame Fire Plume Caught 15 km from Paris

Roux

Cloquet

Tavella

et al. 2023

ACS Earth Space Chem.

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Thanks to the use of filters collected daily in the west of Paris, we confirm the passage of the lead-laden plume following the fire on the roof and spire of Notre-Dame Cathedral in April 2019. The measured concentrations on the filter (Pb = 1.4 μg m −3 ), scanning electron microscopy and Hysplit simulation, correspond to an estimate of a few hundred kilograms of lead that would have been volatilized and then oxidized in the form of micronic and submicronic aerosols. The concentrations found in the plume are, however, much lower than those found in the environment in the 1980s and 1990s but are 100 times higher than those found in times prior to and after the fire. The isotopic signature of the plume is almost identical to that of the fine Pb dust found inside the Notre-Dame building. It is different from the isotopic signature of the Parisian atmosphere before and after the fire, but it is similar to that of the atmospheric Pb legacy recorded by peat cores over the last 300 years in France. The presence of very fine lead-bearing particles makes them potentially transportable over long distances after large urban fires. Our study shows the value of daily aerosol sampling to retrospectively trace the plumes of air pollutants from industrial accidents but also from historical monument fires such as Notre-Dame in 2019.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Section: ■ Results and Discussionmentioning

confidence: 99%

Section: ■ Results and Discussionmentioning

confidence: 99%

See 2 more Smart Citations

Lead from Notre-Dame Fire Plume Caught 15 km from Paris

Roux

Cloquet

Tavella

et al. 2023

ACS Earth Space Chem.

Self Cite

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show abstract

“…To answer this question, a first study was performed on indoor dust samples collected in Notre-Dame after the fire to determine their geochemical signature [10]. This last was approximated from tracers commonly used in the literature to determine the sources of environmental pollution: lead isotopic ratios ( 206 Pb/ 207 Pb; 208 Pb/ 206 Pb) [11][12][13][14] and elemental ones (Sn/Cu; Sb/Cu; Cd/Pb; Cu/Pb) [15,16].…”

Section: Introductionmentioning

confidence: 99%