Determination of the solubilising character of 2-methoxyethyl-(dimethyl)ethylammoniumtris(pentafluoroethyl)trifluorophosphate based on the Abraham solvation parameter model

Calculation of Abraham model L-descriptor and standard molar enthalpies of vaporization and sublimation for C9 - C26 mono-alkyl alkanes and polymethyl alkanes

“…A complete set of solute descriptors enables one to estimate a large number of physicochemical and thermodynamic properties using published Abraham model correlations. To date we have reported mathematical expressions for predicting log K and log P values for solutes dissolved in both traditional molecular organic solvents [39][40][41][42][43] and ionic liquid solvents, [64][65][66][67][68][69][70][71][72][73] molar solubility ratios, [39][40][41][42][43] blood-to-body tissue/fluid partition coefficients, [74][75][76][77][78] Draize scores and eye irritation thresholds, [79][80][81] enthalpies of solvation, [45][46][47][48][49][50][51][52][53][54][55] lethal median concentrations of organic compounds towards fish and other aquatic organisms, [82][83][84][85] nasal pungency, 79,[86]…”

Abraham model ion-specific equation coefficients for the 1-butyl-2,3-dimethyimidazolium and 4-cyano-1-butylpyridinium cations calculated from measured gas-to-liquid partition coefficient data

“…Abraham model correlations have been reported for well over 100 total different tradition organic solvents [29][30][31][32][33][34][35][36][37][38][39][40][41][42][43][44][45][46] and IL organic solvents, [47][48][49][50][51][52][53][54][55][56][57][58][59][60][61] as well as for binary aqueous-ethanol [62] mixtures. Our focus in the present study is IL solvents.…”

“…Our focus in the present study is IL solvents. For neat, anhydrous IL solvents, we have reported IL-specific Abraham model correlations [47][48][49][50][51][52][53][54][55][56][57][58][59][60][61]:…”

Thermochemical investigations of solute transfer into ionic liquid solvents: updated Abraham model equation coefficients for solute activity coefficient and partition coefficient predictions

“…[24][25][26][27][28][29][30][31][32][33][34][35][36][37][38][39] The ion-specific equation coefficients can be combined to allow one to predict solute [40], were used to derive Abraham model log K and log P correlations at 298 K and 323 K. As part of the present study we have also updated the cation-specific and anion-specific equation coefficients published in our earlier papers. The last major revision of the numerical values of the coefficients occurred slightly more than three years ago and was based on a total of 1790 log K and 1760 log P values.…”

“…[22][23][24][25][26][27][28][29][30][31][32][33][34][35][36][37][38][39] The basic model describes solute transfer to an IL solvent both from the gas phase (Eqns. 1 and 2):…”