Determination of the rate constant for homolysis of a nitrone carbon-nitrogen bond via crossover measurements of isotopically labeled substrates. Kinetics properties of caged ambident radicals

Rearrangements of nitrones to O-alkyl oximes via geometrically isomerizing iminoxy radicals

“…Geometric Compositions of VV-Benzhydryl Nitrones (Z)-l and (£)-l and 0-Benzhydryl Oximes (Z)-4 and (£)- " Calculated from first-order rate constants for the /V-benzhydryl nitrones (see Table II). 6 Diethyl carbitol. °Elemental analyses were obtained for these samples.…”