1992
DOI: 10.1016/0022-2852(92)90067-x
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Determination of the molecular structure of sulfonyl chloride isocyanate using microwave spectroscopy

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Cited by 24 publications
(4 citation statements)
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“…This turned our attention to investigate another interesting series, halosulfonyl azides XSO2-NNN (X is F and Cl) in a previous work [13]. From energy optimizations and calculated potential scans fluoro-and chlorosulfonyl azides were predicted to exist only as the gauche conformation similar to the corresponding isocyanates XSO2-NCO [1][2][3][4][5][6]. An identical result we find in the present study on haloselenonyl azides with X being F, Cl and Br.…”
Section: Introductionsupporting
confidence: 70%
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“…This turned our attention to investigate another interesting series, halosulfonyl azides XSO2-NNN (X is F and Cl) in a previous work [13]. From energy optimizations and calculated potential scans fluoro-and chlorosulfonyl azides were predicted to exist only as the gauche conformation similar to the corresponding isocyanates XSO2-NCO [1][2][3][4][5][6]. An identical result we find in the present study on haloselenonyl azides with X being F, Cl and Br.…”
Section: Introductionsupporting
confidence: 70%
“…The conformational behavior of fluorosulfonyl isocyanate F-SO2-NCO and chlorosulfonyl isocyanate Cl-SO2-NCO has drawn the attention of structural chemists and spectroscopists because of their interesting structure and importance in chemistry [1][2][3][4][5][6]. They have been investigated over the past few years by both theoretical and spectroscopic methods.…”
Section: Introductionmentioning
confidence: 99%
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“…On the other hand, a GED study suggested the existence of a second conformer c for ClSO 2 NCO beside conformation b . However, more recent computational and vibrational studies of the gas, liquid, and solid phases did not find any evidence for the existence of a second conformer beside the dominant conformer b …”
Section: Introductionmentioning
confidence: 96%