Abstract. Many palaeoceanographic studies have sought to use the
231Pa∕230Th ratio as a proxy for deep ocean circulation
rates in the North Atlantic. As of yet, however, no study has fully assessed
the concentration of, or controls on, 230Th and 231Pa in
waters immediately following ventilation at the start of Atlantic meridional
overturning. To that end, full water-column 231Pa and
230Th concentrations were measured along the GEOVIDE section,
sampling a range of young North Atlantic deep waters. 230Th and
231Pa concentrations in the water column are lower than those
observed further south in the Atlantic, ranging between 0.06 and
12.01 µBq kg−1 and between 0.37 and 4.80 µBq kg−1,
respectively. Both 230Th and 231Pa profiles generally
increase with water depth from surface to deep water, followed by decrease
near the seafloor, with this feature most pronounced in the Labrador Sea (LA
Sea) and Irminger Sea (IR Sea). Assessing this dataset using extended optimum
multi-parameter (eOMP) analysis and CFC-based water mass age indicates that
the low values of 230Th and 231Pa in water near the
seafloor of the LA Sea and IR Sea are related to the young waters present in
those regions. The importance of water age is confirmed for 230Th
by a strong correlation between 230Th and water mass age (though
this relationship with age is less clear for 231Pa and the
231Pa∕230Th ratio). Scavenged 231Pa and
230Th were estimated and compared to their potential concentrations
in the water column due to ingrowth. This calculation indicates that more
230Th is scavenged (∼80 %) than 231Pa (∼40 %), consistent with the relatively higher particle reactivity of
230Th. Enhanced scavenging for both nuclides is demonstrated near
the seafloor in young overflow waters. Calculation of the meridional transport of
230Th and 231Pa with this new GEOVIDE dataset enables a
complete budget for 230Th and 231Pa for the North
Atlantic. Results suggest that net transport southward of 230Th and
231Pa across GEOVIDE is smaller than transport further south in the
Atlantic, and indicate that the flux to sediment in the North Atlantic is
equivalent to 96 % of the production of 230Th and 74 % of
the production for 231Pa. This result confirms a significantly
higher advective loss of 231Pa to the south relative to
230Th and supports the use of 231Pa∕230Th to
assess meridional transport at a basin scale.