Determination of the composition of copolymers based on vinylazols by UV spectroscopy

Ratovskii, G. V.; Shivernovskaya, O. A.; Biryukova, Ye.I.; Смирнов, А. И.; Izykenova, Galina A.; Kalabina, A. V.

doi:10.1016/0032-3950(87)90400-x

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Copolymerisation Of Vinyltetrazoles1

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2003

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“…53 In the copolymerisation with MMA, an opposite trend is observed. 158 In our opinion, the most correct approach to the study of structure ± activity relationships of vinylazoles in copolymerisation was proposed by Smirnov et al 54,144 Thus for the N-vinylazole Ð diethyl maleate (DEM) and N-vinylazole ± 1-vinylpyrrolidone (VPD) systems, the activities of the monomers in the reaction of vinylazoles with the DEM radical are the higher the higher is the polarity of the C=C bond and the negative charge of the b-carbon atom of the vinyl group of the vinylazole. In contrast, the activities of vinylazoles in the reaction with the VPD radical increase with a decrease in polarity and q b .…”

Section: Copolymerisation Of Vinyltetrazolesmentioning

confidence: 99%