Simultaneous nanometer-scale measurements of the strain and surface undulation distributions of strained Si (s-Si) layers on strain-relief quadruple-Si 1Àx Ge x -layer buffers, using a combined atomic force microscopy (AFM) and tip-enhanced Raman spectroscopy (TERS) system, clarify that an s-Si sample formed by our previously proposed sputter epitaxy method has a smoother and more uniformly strained surface than an s-Si sample formed by gas-source molecular beam epitaxy. The TERS analyses suggest that the compositional fluctuation of the underlying Si 1Àx Ge x buffer layer is largely related to the weak s-Si strain fluctuation of the sputtered sample. # 2011 The Japan Society of Applied Physics E lectron and hole mobilities in Si are enhanced by the introduction of strain. Biaxial global-strain-type strained Si (s-Si) formed on a Si 1Àx Ge x strain-relief relaxed buffer has been intensively applied to high-electronmobility transistors such as modulation-doped field-effect and metal-oxide-semiconductor transistors. [1][2][3][4][5] However, when we form global-strain-type s-Si by currently used gas-source methods such as gas-source molecular beam epitaxy (GS-MBE) and chemical vapor deposition (CVD), a crosshatch undulation pattern is generally formed on the surface with an undulation pitch of typically less than 1 m.6) This surface undulation causes a nonuniform strain distribution 7) and variations in the physical properties and device performance on the surface. This is a serious issue to be solved for smaller and higher-density devices.Recently, we have proposed a stepwise quadrupleSi 1Àx Ge x -layer buffer (QL buffer) as a strain-relief relaxed buffer.8) A smoother s-Si surface has been obtained on the QL buffer by our proposed sputter epitaxy method, which uses a combination of ultrahigh-vacuum-compatible magnetron sputtering and an Ar/H 2 mixture working gas, than by GS-MBE. 9) Therefore, this s-Si surface formed by our sputter epitaxy method is expected to have a more uniform strain distribution.Raman spectroscopy is one of the useful techniques for evaluating the surface strain distribution; however, its conventional spatial resolution is limited to about 1 Â 1 m 2 due to the diffraction limit and it is difficult to evaluate the s-Si surface strain distribution with an undulation pitch of .1 m.To obtain a higher spatial resolution, we have applied a near-field and plasmon oscillation coupling method 10,11) and introduced a combined atomic force microscopy (AFM) and tip-enhanced Raman spectroscopy (TERS) system for simultaneous measurements of surface topography and the enhanced Raman shift spectrum for an s-Si surface. So far, there has been one report, using a similar AFM-TERS system, on strain variation at the nanometer scale within a 1.4 m crosshatch segment on the s-Si surface on a Si 1Àx Ge x graded buffer.
11)In this paper, using the AFM-TERS method, we first report the relationship between the surface roughness and the strain distribution, on the nanometer scale, of strained Si on the stepwise QL bu...