2024
DOI: 10.1002/cite.202400095
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Determination of Chain Transfer Constants of Alcohols for High‐Pressure Polyethylene Polymerization

Laura Euler Bueno,
Kristina Maria Zentel,
Markus Busch

Abstract: In low‐density polyethylene (LDPE) production, low‐molecular‐weight species are used as chain transfer agents (CTAs). They reduce the degree of polymerization, which has an impact on the polymer properties, such as processability. To specifically adjust the product properties, a detailed understanding of the transfer kinetics to CTAs is indispensable. Thus, the transfer activity of various primary, secondary, and tertiary alcohols as well as diols was investigated experimentally between 120 °C and 250 °C at 20… Show more

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