In mine safety and health research, psychological issues have always been neglected. This paper aims to identify the psychological perceptions of workers with respect to the mine environment and interpersonal environment across the whole production system. A survey was designed that measured the miners’ demographic details and perceptions of two affect-based interactions; three resource-based interactions for the manager, supervisor, co-worker; and three actual environment interactions. A total of 642 frontline coal miners from six mines located in six provinces in China completed the survey. The main results indicated that that miners reported low psychology status, especially those over 51 years old, with a monthly income of 2000–4000 and junior school education. Second, there was a high proportion of inferior value in environmental interactions. Meanwhile, the miners’ interactions with their co-workers were perceived as the most positive and those with their managers as the least in interpersonal interactions. Third, there were significant differences in sub-dimension interactions (actual environment, resource-based, affect-based interactions) that certainly existed in these interactive roles. Additionally, the dissociated type of miners with manager and supervisor (low resource and affect-based interaction) reached 23.99~24.45%. This study revealed the inner psychological risk factors for safety and health work in coal mines and provides an essential guideline for mining industries.