Liquid-to-air membrane
energy exchangers (LAMEEs) are promising
in heating, ventilating, and air-conditioning applications because
they are able to use semipermeable membranes to transfer heat and
moisture between air and liquid desiccant streams. However, the development
of crystallization fouling in membranes may pose a great risk to the
long-term performance of LAMEEs. The main aim of this paper is to
characterize the evolution of crystallization fouling in membranes
through the use of both noninvasive and invasive methods. Noninvasive
methods are used to study the development of fouling in the LAMEE
by monitoring the changes in moisture flux through the membrane and
overall moisture-transfer resistance of the LAMEE. On the other hand,
invasive methods are implemented to characterize fouled membranes
by using optical microscopy and scanning electron microscopy (SEM)
to depict the morphology of crystal deposits and energy-dispersive
X-ray spectroscopy (EDX) to identify the composition of the deposits.
Experiments are performed by using air to dehydrate MgCl
2
(aq) at two operating conditions of low and high fouling rates. The
results show that the moisture flux decreases and the moisture-transfer
resistance increases more considerably during the test at the high
fouling rate than in the test at the low fouling rate. SEM micrographs
show that cake crystal deposits cover the membrane surface in the
test at the high fouling rate, whereas only few crystal particles
are observed on the membrane in the test at the low fouling rate.
Furthermore, the crystal deposits undergo more structural changes
in the tests at the high fouling rate than in the tests at the low
fouling rate, possibly because of the higher moisture transfer rate
through the membrane in the tests at the high fouling rate. Finally,
the SEM–EDX analysis confirms that the crystal deposits primarily
consist of Mg, Cl, and O elements.