We report production rates, rotational temperatures, and related parameters for gases in C/2013 R1 (Lovejoy) using the Near InfraRed SPECtrometer at the Keck Observatory, on six UT dates spanning heliocentric distances (R h ) that decreased from 1.35 AU to 1.16 AU (pre-perihelion). We quantified nine gaseous species (H 2 O, OH * , CO, CH 4 , HCN, C 2 H 6 , CH 3 OH, NH 3 , and NH 2 ) and obtained upper limits for two others (C 2 H 2 and H 2 CO). Compared with organics-normal comets, our results reveal highly enriched CO, (at most) slightly enriched CH 3 OH, C 2 H 6 , and HCN, and CH 4 consistent with "normal", yet depleted, NH 3 , C 2 H 2 , and H 2 CO. Rotational temperatures increased from ∼50 K to ∼70 K with decreasing R h , following a power law in R h of −2.0 ± 0.2, while the water production rate increased from 1.0 to 3.9 × 10 28 molecules s −1 , following a power law in R h of −4.7 ± 0.9. The ortho-para ratio for H 2 O was 3.01 ± 0.49, corresponding to spin temperatures (T spin ) 29 K (at the 1σ level). The observed spatial profiles for these emissions showed complex structures, possibly tied to nucleus rotation, although the cadence of our observations limits any definitive conclusions. The retrieved CO abundance in Lovejoy is more than twice the median value for comets in our IR survey, suggesting this comet is enriched in CO. We discuss the enriched value for CO in comet C/2013 R1 in terms of the variability of CO among Oort Cloud comets.