Detailed analysis of the essential oil from Cistus albidus L. by combination of GC/RI, GC/MS and 13C-NMR spectroscopy

Paolini, Julien; Tomi, Pierre; Bernardini, Antoine‐François; Bradesi, Pascale; Casanova, Joseph; Kaloustian, J.

doi:10.1080/14786410701766083

Cited by 17 publications

(49 citation statements)

References 34 publications

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“…High amounts of thymol and carvacrol were exclusive to the pollen (Maccioni et al, 2007). Only a small proportion of oxygenated monoterpenes (0.2%), but no monoterpene hydrocarbons, was identified in C. albidus leaves that grow in nature in France (Paolini et al, 2008). In another work, many monoterpenes, including 3-carene, camphene, cis -linalool oxide, cis -thujone, tricyclene, verbenone, and α-thujene and traces of borneol were detected in Mediterranean C. albidus leaves (Ormeño et al, 2007).…”

Section: Chemical Analysesmentioning

confidence: 99%

“…Chemical analysis of C. albidus tissue and essential oil preparations in north-eastern Spain, France and Italy showed high content of sesquiterpenes, in particular, β-sesquiphellandrene, β-caryophyllene, β-bourbonene, α-zingiberene, and germacrene D (Robles and Garzino, 1998; Maccioni et al, 2007; Paolini et al, 2008; Llusià et al, 2010). Among them, α -zingiberene and germacrene D were the most abundant, while epi -10-γ-eudesmol was detected uniquely in flowers, 1- epi -cubenol only in leaves, and β-himachalene exclusively in flower tops (Maccioni et al, 2007).…”

Section: Chemical Analysesmentioning

confidence: 99%

“…Only a small fraction of the essential oil composition of C. albidus plants collected in south France and Spain contained diterpenes (Paolini et al, 2008; Llusià et al, 2010). Among them the largest concentration was measured for the labdane-type compound 13- epi -manoyl oxide (Paolini et al, 2008).…”

Section: Chemical Analysesmentioning

confidence: 99%

“…Among them the largest concentration was measured for the labdane-type compound 13- epi -manoyl oxide (Paolini et al, 2008). Chemical analysis of the aerial parts and essential oil of Cistus creticus subsp.…”

Section: Chemical Analysesmentioning

confidence: 99%

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Genus Cistus: a model for exploring labdane-type diterpenes' biosynthesis and a natural source of high value products with biological, aromatic, and pharmacological properties

et al. 2014

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The family Cistaceae (Angiosperm, Malvales) consists of 8 genera and 180 species, with 5 genera native to the Mediterranean area (Cistus, Fumara, Halimium, Helianthemum, and Tuberaria). Traditionally, a number of Cistus species have been used in Mediterranean folk medicine as herbal tea infusions for healing digestive problems and colds, as extracts for the treatment of diseases, and as fragrances. The resin, ladano, secreted by the glandular trichomes of certain Cistus species contains a number of phytochemicals with antioxidant, antibacterial, antifungal, and anticancer properties. Furthermore, total leaf aqueous extracts possess anti-influenza virus activity. All these properties have been attributed to phytochemicals such as terpenoids, including diterpenes, labdane-type diterpenes and clerodanes, phenylpropanoids, including flavonoids and ellagitannins, several groups of alkaloids and other types of secondary metabolites. In the past 20 years, research on Cistus involved chemical, biological and phylogenetic analyses but recent investigations have involved genomic and molecular approaches. Our lab is exploring the biosynthetic machinery that generates terpenoids and phenylpropanoids, with a goal to harness their numerous properties that have applications in the pharmaceutical, chemical and aromatic industries. This review focuses on the systematics, botanical characteristics, geographic distribution, chemical analyses, biological function and biosynthesis of major compounds, as well as genomic analyses and biotechnological approaches of the main Cistus species found in the Mediterranean basin, namely C. albidus, C. creticus, C. crispus, C. parviflorus, C. monspeliensis, C. populifolius, C. salviifolius, C. ladanifer, C. laurifolius, and C. clusii.

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Section: Chemical Analysesmentioning

confidence: 99%

Section: Chemical Analysesmentioning

confidence: 99%

Section: Chemical Analysesmentioning

confidence: 99%

Section: Chemical Analysesmentioning

confidence: 99%

See 2 more Smart Citations

Genus Cistus: a model for exploring labdane-type diterpenes' biosynthesis and a natural source of high value products with biological, aromatic, and pharmacological properties

et al. 2014

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“…The relevance of these papers lies on the different issues explored, such as the determination of plant chemotypes [100,108,111,114], biological activity [99,[101][102][103][104], chemical composition [105,107,110,[112][113] and interaction plant-environment [106,109], which couldn't be achieved in the past when gas chromatography was still a young technique. Besides the new capabilities offered by GC-MS and described in this paragraph, the main advances of the technique are due to the introduction of capillary columns, to the developments of faster electronics and, more in general, to the improvement of technology.…”

Section: Gc-msmentioning

confidence: 99%

Advances of Modern Gas Chromatography and Hyphenated Techniques for Analysis of Plant Extracts

Costa¹,

Dugo²,

Santi³

et al. 2010

COC

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Modern gas chromatography, with the development of advanced analytical techniques, has become a fundamental tool for the separation and characterization of plant extracts. These last issues are absolutely important if considering the widespread use of plant derivatives not only in pharmaceutical/food industry but also, for a large part, in traditional and alternative medicine, which require a high level of quality and safety. Hence, the development of new, powerful hyphenated GC techniques were reviewed in this article, including Gas Chromatography-Mass Spectrometry (GC-MS), Solid Phase Microextraction-Gas Chromatography (SPME-GC), Gas Chromatography-Fourier-transformed Infrared Spectroscopy (GC-FTIR), Multidimensional Gas Chromatography (MDGC) and Comprehensive Gas Chromatography (GCxGC). Several applications of each technique were reported and illustrated.

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Host Plant Perception and Selection in the Sibling Species Macrolophus melanotoma and Macrolophus pygmaeus (Hemiptera: Miridae)

et al. 2016

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The electroantennogram responses (EAGs) of Macrolophus melanotoma and Macrolophus pygmaeus (Hemiptera: Miridae) exposed to volatile compounds (VOCs) of host and non-host plants were compared. The VOCs were identified by gas chromatography. Hosts and nonhosts eliciting similar EAGs were tested in olfactory assays against plants without a significant EAGs for the two Macrolophus species. No characteristic VOC profile was found for hosts and non-hosts. Terpenes predominated in many hosts and carboxylic acids in nonhosts, but no specific VOCs were characteristic of host plants. Significant EAGs (maximum deflection values in mV) were recorded in plants with very different VOC profiles, both hosts and non-hosts. The EAGs were higher for M. melanotoma than for M. pygmaeus, and were higher for males than for females. In M. melanotoma the EAGs were greater with hosts than with non-hosts, but they were similar in M. pygmaeus. The EAGs were correlated with the concentrations of sesquiterpenes and alcohols in both species. In olfactory assays, M. melanotoma and M. pygmaeus preferred their respective hosts, but they did not discriminate between non-host with and without significant EAGs. According to the results, Macrolophus species are expected to rely on ubiquitous VOCs for the identification of their hosts. The variation in the EAGs between M. melanotoma and M. pygmaeus is attributed to the variation in the proportions of olfactory receptor neurones with different sensitivity to VOCs (e.g. sesquiterpenes). Host plant selection is discussed in the light of the perception of VOCs and the processing of information by the central nervous system. 28 20 * α-copaene 1581 1450 2.5±0.5

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Detailed analysis of the essential oil from Cistus albidus L. by combination of GC/RI, GC/MS and ¹³C-NMR spectroscopy

Cited by 17 publications

References 34 publications

Genus Cistus: a model for exploring labdane-type diterpenes' biosynthesis and a natural source of high value products with biological, aromatic, and pharmacological properties

Genus Cistus: a model for exploring labdane-type diterpenes' biosynthesis and a natural source of high value products with biological, aromatic, and pharmacological properties

Advances of Modern Gas Chromatography and Hyphenated Techniques for Analysis of Plant Extracts

Host Plant Perception and Selection in the Sibling Species Macrolophus melanotoma and Macrolophus pygmaeus (Hemiptera: Miridae)

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