2010
DOI: 10.1016/j.jnoncrysol.2010.04.057
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Design of oxy-fluoride glass-ceramics containing NaLaF4 nano-crystals

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Cited by 75 publications
(76 citation statements)
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“…A similar study was reported by Sroda,95 in the crystallization process of NaLaF 4 , affected by Er 3z ions. de Pablos-Martín et al 96 described the crystallisation mechanism of NaLaF 4 and the formation of a diffusional barrier, similar to those work reported in Refs. 44, 82 and 90.…”
supporting
confidence: 76%
“…A similar study was reported by Sroda,95 in the crystallization process of NaLaF 4 , affected by Er 3z ions. de Pablos-Martín et al 96 described the crystallisation mechanism of NaLaF 4 and the formation of a diffusional barrier, similar to those work reported in Refs. 44, 82 and 90.…”
supporting
confidence: 76%
“…The described mechanism is an example of a self‐organized process. It should be noted, however, also in nonphase separated oxyfluoride glasses, as shown for the systems with BaF 2 and LaF 3 , in the amorphous matrix Ba‐F as well as La‐F structures are already formed …”
Section: Strategies For the Formation Of Nanocrystalline Glass‐ceramicssupporting
confidence: 52%
“…In these studies, the formation of core/shell structures is described which form spontaneously and lead to a drastic increase in the viscosity of these shells and to the formation of stresses which decelerate further crystal growth. This has been performed for the crystallization of oxides (Fe 3 O x, quartz or spodumen) or of fluorides (CaF 2, SrF 2, BaF 2, LaF 3, or NaREF 4 ). In all these systems, the viscosity of the residual glassy phase increases during the course of nucleation and crystal growth.…”
Section: Introductionmentioning
confidence: 99%
“…The formation of these nano-crystals should be ascribed to a diffusion layer which acts as the barrier to hamper the further crystal growth [16][17][18]. In detail, the diffusion layer around Na 2 MgSiO 4 is enriched in the glass-forming components since the present samples belong to non-isochemical glass system, and this increases the viscosity, and hence, hinders the diffusion of modifying ions (e.g.…”
Section: Resultsmentioning
confidence: 87%