Phase velocity compensation technologies using asymmetric coplanar waveguides (ACPW) with or without defected ground structures (DGS) are proposed to enhance the directivity of wideband 3-dB broadside-coupled coplanar waveguide (BC CPW) couplers. First, even-and odd-mode analyses of BC CPW couplers with four shunt capacitors are performed to obtain closed-form design formulas. Then, ACPW instead of the shunt capacitors are inserted to the input and output ports of the coupler to improve the directivity. Lastly, DGS combining with ACPW are applied to further improve the directivity and broaden the bandwidth. The measured results show that only using ACPW, the bandwidth for the directivity of better than 20 dB is 44.2% with a maximum directivity of 42.6 dB. When both ACPW and DGS are used, the bandwidth for the directivity of better than 20 dB is 63.3%, and that for the directivity of better than 30 dB is enhanced to 21.3% with a maximum directivity of 55.9 dB, which is more than 10 dB over the existing BC CPW couplers.