“…A number of alternative memory technologies, namely magnetic random access memory (MRAM) and ferroelectric RAM (FeRAM) have achieved higher programming performance than fl ash, but scaling-down these technologies remains challenging. [ 3,4 ] Recently, ferroelectric tunnel junction (FTJ) devices emerged as an alternative memory technology, attracting much attention of solid-state physicists and materials scientists. Conceptualized in the 1970s by Esaki et al, [ 5 ] it has been experimentally demonstrated that when an ultrathin ferroelectric fi lm serves as barrier layer in tunnel junction devices, the quantum-mechanical tunneling current and resistance can be manipulated nondestructively via the polarization direction of the ferroelectric Figure 1 c also shows that the layer between the silicon and the STO is amorphous.…”