A computer-aided design modeling is presented to compute a shunt capacitance and series inductance of π or T-equivalent network parameters of microstrip step-discontinuity at a junction on multilayer iso/anisotropic substrates. The results of the proposed model of shunt capacitance and series inductance have shown permissible agreement with simulation results by the average deviation of 4.5% and 4.9% for 1 < ε r ≤ 40 and w 1 /w 2 < 10 respectively. Similarly, the transient signal propagation characteristics, such as arrival time of the pulse, rise-time, delay time, settling time, etc. are influenced by the anisotropy in the transmission line and said information's are also important for proper characterization of analog/ digital pulses on multilayer iso/anisotropic substrate planar transmission lines. The time-domain characteristic of transient pulses over microstrip stepped line with diverse conditions are strengthening the concept of interconnects, which plays a vital role in modern circuit technology. Proposed modeling concept is more accurate to design of contemporary planar microwave filters, impedance matching networks and VLSI interconnects.