“…Tu et al 19 found that ternary MgAlFe-LDHs had a better removal effect of U( vi ) as compared to binary MgAl-LDHs. Cheng et al 20 systematically studied the effects of intercalation anions (CO 3 2− , PO 4 3− and SO 4 2− ) on the U( vi ) removal performance of MgAl-LDHs, and MgAl-LDHs adjusted by CO 3 2− were the most effective for U( vi ) purification. The exploration of the properties of LDH materials could have broad prospects for the application of U( vi ) decontamination.…”
Section: Introductionmentioning
confidence: 99%
“…Tu et al 19 found that ternary MgAlFe-LDHs had a better removal effect of U(VI) as compared to binary MgAl-LDHs. Cheng et al 20 The metal octahedra in LDHs are interconnected by metaloxygen-metal oxo-bridging linkages and serve as visible-lightinduced photocatalytic redox centers, which refer to the transfer of excited electrons from one metal to another. The interlayer space in LDHs plays a key role in enhancing the photocatalytic activities, which is conducive to the participation of photogenerated charge carriers in the reaction and inhibition of charge recombination.…”
The low-cost NiAl exhibits high efficiency for U(vi) decontamination, involving surface complexation and photocatalytic reduction. The photogenerated electrons and generated ˙O2− radicals reduced the absorbed U(vi) into insoluble UO2(s) and U3O8.
“…Tu et al 19 found that ternary MgAlFe-LDHs had a better removal effect of U( vi ) as compared to binary MgAl-LDHs. Cheng et al 20 systematically studied the effects of intercalation anions (CO 3 2− , PO 4 3− and SO 4 2− ) on the U( vi ) removal performance of MgAl-LDHs, and MgAl-LDHs adjusted by CO 3 2− were the most effective for U( vi ) purification. The exploration of the properties of LDH materials could have broad prospects for the application of U( vi ) decontamination.…”
Section: Introductionmentioning
confidence: 99%
“…Tu et al 19 found that ternary MgAlFe-LDHs had a better removal effect of U(VI) as compared to binary MgAl-LDHs. Cheng et al 20 The metal octahedra in LDHs are interconnected by metaloxygen-metal oxo-bridging linkages and serve as visible-lightinduced photocatalytic redox centers, which refer to the transfer of excited electrons from one metal to another. The interlayer space in LDHs plays a key role in enhancing the photocatalytic activities, which is conducive to the participation of photogenerated charge carriers in the reaction and inhibition of charge recombination.…”
The low-cost NiAl exhibits high efficiency for U(vi) decontamination, involving surface complexation and photocatalytic reduction. The photogenerated electrons and generated ˙O2− radicals reduced the absorbed U(vi) into insoluble UO2(s) and U3O8.
Owing to the flexible adjustability of laminates, layered double hydroxides (LDHs) can achieve enhanced conductivity and capacitance. However, the regulation of interlayer activity is a great challenge because of the unconquerable charge repulsion between laminates. Herein, a dual‐activity design of LDHs is uniquely realized, including laminate defects and interlayer ZnS quantum dots (QDs). Via pre‐embedding Zn2+ and controllable vulcanization, ZnS‐QDs interpenetrate between CuCo‐LDH layers, exposing abundant active sites and widening the layer spacing. Meanwhile, sulfur replaces part of the oxygen on the laminates to form rich oxygen vacancies (CuCo‐LDH‐S), which does not damage the layered spatial structure and ensures the fast ions/electron transport. Theoretical calculations indicate that the new active centers exhibit higher charge density as compared to CuCo‐LDH. Moreover, the copper foam directly provides copper source to ensure that CuCo‐LDH‐S/ZnS‐QDs present a 3D self‐supporting structure with ultrastability. Hence, it delivers an ultrahigh capacitance of 7.82 F cm−2 at 2 mA cm−2 and 4.43 F cm−2 at 20 mA cm−2. The hybrid supercapacitors display an outstanding energy density of 299 µWh cm−2 at power density of 1600 µW cm−2, with outstanding capacitance retention of 102.3% and coulomb efficiency of 96.2% after 10 000 cycles.
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