“…Hydrogen can be extracted via reforming processes of HAc via three major routes: steam reforming (SR), catalytic partial oxidation (CPOX), and autothermal reforming (ATR), as listed in eqs –. In contrast to endothermic SR with the requirement of high external heat energy and exothermic CPOX with a low hydrogen yield, the ATR process, which balances the reaction heat through regulating oxygen in feed, presents a higher energy efficiency and shows economical preferability. , Nonprecious metal catalysts, such as nickel-based catalysts, have been widely investigated due to their excellent activity in cleavage of C–C and C–H bonds within hydrocarbons for the reforming process. − Nevertheless, with O 2 in the feed of ATR, the active metal can be easily sintered and oxidized; besides, more significantly, carbon deposition is the main deactivation cause of nickel-based catalysts, which is specifically prominent when acetic acid is in the feed, due to the oxygenated nature of pyrolysis volatiles (eqs –) . In our previous studies, the structure–performance relationships of various Ni- or Co-based catalysts were explored to guide the design of the catalyst structure. , It is reasonable to demonstrate that increasing the dispersion of the active metal along with enhancing the interaction between Ni/Co particle-support is crucial to resisting sintering. , Besides, the oxidation of Ni 0 was proved to be inhibited by the electron transformation from WO 2 to the Ni on the WO 2 –Ni interface, elucidating that the construction of electron transfer between the Ni particle and the support effectively facilitated the antioxidant capacity of the catalysts .…”