Design and Synthesis of Heterogeneous Frustrated Lewis Pairs for Hydrogenation: From Molecular Immobilization to Defects Engineering
Miaomiao Chen,
Min Wang,
Min Ji
Abstract:The concept of “Frustrated Lewis pairs” (FLPs), which emerged from the discovery that H2 can be reversibly activated by combinations of sterically encumbered Lewis acids and bases. Since then, the field of FLP chemistry has expanded enormously. One of the most remarkable achievements is the development of FLP catalysts for hydrogenation, which are environmentally friendly and have potential industrial application prospects. In recent years, this unique catalysis concept has pushed the study of FLP chemistry to… Show more
This review provides an overview of FLP chemistry in the field of CO2 hydrogenation, whichcovers both experimental and computational aspects, while ranging from homogeneous catalysis to recent heterogenisation strategies in porous solids.
This review provides an overview of FLP chemistry in the field of CO2 hydrogenation, whichcovers both experimental and computational aspects, while ranging from homogeneous catalysis to recent heterogenisation strategies in porous solids.
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