Design and Synthesis of Conducting Polymer Bio-Based Polyurethane Produced from Palm Kernel Oil

Munir, Muhammad Abdurrahman; Badri, Khairiah Haji; Heng, Lee Yook; Inayatullah, Ahlam; Badrul, Hamid Alkhair; Emelda, Emelda; Dwinta, Eliza; Kusumawardani, Nurul; Wulandari, Ari Susiana; Aprilia, Veriani; Supriyono, Rachmad Bagas Yahya

doi:10.1155/2022/6815187

Cited by 10 publications

(10 citation statements)

References 66 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In this study, the SPE was employed as the working electrode, while Ag/AgCl with a double-junction system and platinum wire were the reference and auxiliary electrodes, respectively. 27 The present study acquired phosphate buffer solution (PBS) by mixing sodium dihydrogen phosphate (Na 2 H 2 PO 4 ) and disodium hydrogen phosphate (Na 2 HPO 4 ), which were both purchased from Merck, Sdn. Bhd.…”

Section: Methodsmentioning

confidence: 99%

“…Potassium hexacyanoferrate III (K 3 [Fe(CN 6 ]) and potassium hexacyanoferrate II-3-hydrate (K 4 [Fe(CN 6 ] 3H 2 O) were obtained from Merch Sdn. Bhd., sulfuric acid (H 2 SO 4 ) (≥97%) and lithium perchlorate were purchased from Sigma Aldrich, and PU was produced according to the procedure outlined by Munir et al 27 The present study acquired phosphate buffer solution (PBS) by mixing sodium dihydrogen phosphate (Na 2 H 2 PO 4 ) and disodium hydrogen phosphate (Na 2 HPO 4 ), which were both purchased from Merck, Sdn. Bhd.…”

Section: Methodsmentioning

confidence: 99%

“…The PU is a unique polymer with several advantages, including good stability, ease of production, low cost, and good electrical properties, thus making it applicable for histamine detections that utilize electrochemical sensors. 27 The MIP film in this study was acquired by choosing the best parameters to develop a PU-based imprinted film. The electrochemical sensor was also validated, verified, and subsequently employed to analyze histamine in selected samples.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Inspecting Histamine Isolated from Fish through a Highly Selective Molecularly Imprinted Electrochemical Sensor Approach

Munir¹,

Rahmawati

Jamal

et al. 2023

ACS Omega

Self Cite

View full text Add to dashboard Cite

Numerous analytical approaches have been developed to determine histamine levels in food samples due to its health consequences. Consuming histamine over the Food and Drug Administration (FDA)-regulated 50 mg kg −1 limit would result in chronic toxicity. Consequently, the present study discusses a novel electrochemical approach to evaluate histamine levels in fish products via a molecularly imprinted polymer (MIP) on an electrode surface. The film was produced with electropolymerized polyurethane (PU), which maintained the histamine compound. Fourier-transform infrared (FTIR) spectroscopy was applied to verify the MIP manufactured in this study. The capability of the polymer was measured by assessing its electron shifts with cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Differential pulse voltammetry (DPV) was also employed to validate the sensing method. The MIP/ screen-printed electrode (SPE) and non-imprinted polymer (NIP)/SPE recorded a linear response ranging from 1 to 1000 nmol L −1 at the 1.765 and 709 nmol L −1 detection limits. The sensing technique was subsequently utilized to determine the histamine levels in selected samples at room temperature (25 °C). Generally, the sensor allowed the accurate and precise detection of histamine in the fish samples. Furthermore, the approach could be categorized as a simple technique that is low-cost and suitable for on-site detections.

show abstract

Section: Methodsmentioning

confidence: 99%

Section: Methodsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Inspecting Histamine Isolated from Fish through a Highly Selective Molecularly Imprinted Electrochemical Sensor Approach

Munir¹,

Rahmawati

Jamal

et al. 2023

ACS Omega

Self Cite

View full text Add to dashboard Cite

show abstract

“…Bhd. Sulfuric acid (H 2 SO 4 ), ≥97%, and lithium perchlorate were purchased from Sigma Aldrich, and polyurethane (PU) was produced by Munir et al [ 36 ]. The phosphate buffer solution (PBS) was obtained by the combination of sodium dihydrogen phosphate (Na 2 H 2 PO 4 ) and disodium hydrogen phosphate (Na 2 HPO 4 ), and both reagents were purchased from Merck, Sdn.…”

Section: Methodsmentioning

confidence: 99%

“…This study conveys an electrochemical sensor for histamine detection on-site for the first time through the combination of MIP material with electropolymerized polyurethane (PU). PU is a unique polymer that has several advantages, such as good stability, being easily produced, being inexpensive, and having sufficient electrical properties that can be applied for histamine detection using the electrochemical sensor approach [ 36 ]. Furthermore, the MIP film was acquired by choosing the best states to develop a polyurethane-based imprinted film.…”

Section: Introductionmentioning

confidence: 99%

Polyurethane Application to Transform Screen-Printed Electrode for Rapid Identification of Histamine Isolated from Fish

Munir¹,

Jamal

Said

et al. 2023

Scientifica

Self Cite

View full text Add to dashboard Cite

The toxicity of histamine has attracted numerous researchers to develop a method for histamine determination purposes. The Food and Drug Administration (FDA) unequivocally prohibits the consumption of histamine above 50 mg·kg−1. Thus, an innovation in histamine detection in fish has been developed in this research. The investigation of the histamine level in fish has been conducted by using an electrochemical sensor approach and producing a polymer via molecularly imprinted polymer (MIP) on a screen-printed electrode. The technique was validated by assessing the shifts in electron shifting using the cyclic voltammetry (CV) approach and electrochemical impedance spectroscopy (EIS), whereas differential pulse voltammetry (DPV) was applied to validate the sensor method. The instruments showed a linear response ranging from 1–1000 nmol·L−1, with a detection limit of MIP/SPE at 1.765 nmol·L−1 and 709 nmol·L−1 for the NIP/SPE, respectively. The sensing technique was employed to determine the histamine level in selected samples at room temperature (25°C). The outcomes of this study indicated that the validated chemical sensor allowed accurate and precise detection of fish samples and can be categorized as a simple approach. The instrument is inexpensive and suitable for on-site detection.

show abstract

Synthesis, physicochemical and thermal properties of urethane‐modified polyesteramide films using mahua and castor oil as sustainable resources

Ganvit,

Patel,

Patel

et al. 2023

J of Applied Polymer Sci

View full text Add to dashboard Cite

In this work, a number of urethane‐modified polyesteramide (UmPEA) films were developed from mahua and castor oils, which are renewable resources. Mahua oil and diethanolamine were reacted to form mahua fattyamide, which was then reacted with itaconic acid to prepare polyesteramide. In order to make the UmPEA films, different proportions of polyesteramide and castor oil as polyols were reacted with isophoronediisocyanate. The UmPEA films showed excellent chemical resistance against water, acid, alkali, salt, and organic solvents and were found insoluble in common organic solvents. The thermal stability of the UmPEA films was investigated through TGA and DSC analyses, and their Tg values are between 69.1°C and 56.1°C for UmPEA films, which indicated that a higher content of CO enhances the Tg, and it was also found that the films were highly stable up to 230°C. The Ea values [224 kJ mol−1 (Tp1) and 226 kJ mol−1 (Tp2)] indicate that the castor oil enhances the thermal stability of the films due to better cross‐linking density occurring through the high hydroxyl groups of CO as the polyol which also showed better flame retardancy in the synthesized UmPEA films. Our findings demonstrate that the newly developed UmPEA films can be potent coating materials.

show abstract

Design and Synthesis of Conducting Polymer Bio-Based Polyurethane Produced from Palm Kernel Oil

Cited by 10 publications

References 66 publications

Inspecting Histamine Isolated from Fish through a Highly Selective Molecularly Imprinted Electrochemical Sensor Approach

Inspecting Histamine Isolated from Fish through a Highly Selective Molecularly Imprinted Electrochemical Sensor Approach

Polyurethane Application to Transform Screen-Printed Electrode for Rapid Identification of Histamine Isolated from Fish

Synthesis, physicochemical and thermal properties of urethane‐modified polyesteramide films using mahua and castor oil as sustainable resources

Contact Info

Product

Resources

About