Design and synthesis of a novel d10–d10 mixed metal-based polymer with superior luminescent properties to select Ca2+ and Zn2+

Qu, Jie; Gu, Wen; Coxon, Paul R.; Coto, Mike; Liu, Xin; Xi, Kai; Yuan, Ningyi; Ding, Jianning

doi:10.1016/j.inoche.2015.02.003

Cited by 1 publication

(2 citation statements)

References 35 publications

(21 reference statements)

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“…Sequential or multistep deposition allows thin film formation. In this context, a tetracyanonickelate-based 2D-layered MOF, {Fe(py) 2 MII(CN) 4 } (py = pyridine; M═Ni (83), Pd (84), Pt (85)) and {Fe(pz)MII(CN) 4 } (pz = pyrazine; M═Ni (86), Pd (87), Pt (88)), thin films was reported by Sakaida et al [126] An Fe 2+ ion coordinated by the squareplanar tetracyanometallate ion generates 2D sheets of both compounds. The stacking of the 2D sheets is facilitated by a Nterminated ligand which coordinating to Fe 2+ axial positions.…”

Section: Thin-film Depositionmentioning

confidence: 99%

“…A Ag‐Cu ‐based CN‐CP [Cu II (DMF) 4 ](CN) 2 CuI 2 [Ag 2 (CN) 4 ] ( 16 ) has been synthesized by Qu and his colleagues. [ 84 ] The Cu (II) was partially deoxidized into Cu(I) in the reaction producing a Cu(I) and Cu (II) ratio of 2:1 with a crystallized polymer in a monoclinic system. Two different coordination geometries were displayed through Cu ions.…”

Section: Synthetic Approaches Of Hofmann‐type Cn‐cpsmentioning

confidence: 99%

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Hofmann‐Type Cyanide Bridged Coordination Polymers for Advanced Functional Nanomaterials

Hegazy,

Hassan,

2023

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Since the discovery of Hofmann clathrates of inorganic cyanide bridged coordination polymers (Hofmann‐type CN‐CPs), extensive research is done to understand their behavior during spin transitions caused by guest molecules or external stimuli. Lately, research on their nanoscale architectures for sensors and switching devices is of interest. Their potential is reported for producing advanced functional inorganic materials in two‐dimensional (2D) morphology using a scalable solid‐state thermal treatment method. For instance, but not restricted to, alloys, carbides, chalcogenides, oxides, etc. Simultaneously, their in situ crystallization at graphene oxide (GO) nanosheet surfaces, followed by a subsequent self‐assembly to build layered lamellar structures, is reported providing hybrid materials with a variety of uses. Hence, an overview of the most recent developments is presented here in the synthesis of nanoscale structures, including thin films and powders, using Hofmann‐type CN‐CPs. Also thoroughly demonstrated are the most recent synthetic ideas with the modest control over the size and shape of nanoscale particles. Additionally, in order to create new functional hybrid materials for electrical and energy applications, their thermal decomposition in various environments and hybridization with GO and other guest molecules is examined. This review article also conveyed their spin transition, astounding innovative versatile adhesives, and structure features.

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