When epitaxial silicon is deposited on highly doped substrates, impurity atoms transfer from the substrate to the growing epitaxial film. This transfer, usually referred to as autodoping, may establish a lower limit on the dopant concentration in the epitaxial film and may prevent the formation of an abrupt doping profile. We have studied the transfer of arsenic during the deposition of epitaxial silicon by the pyrolysis of silane at a temperature of 1050° C. The amount of autodoping is determined from the flat portion of the doping profile and has been studied as a function of the substrate dopant concentration. The data are interpreted in terms of solid‐state diffusion theory by assuming that during deposition the arsenic diffuses to the back of the substrate, evaporates from the back surface, transfers in the gas phase to the front surface, and then is incorporated into the film. Calculations indicate that 0.9% of the arsenic that evaporates from the back surface is deposited into the epitaxial film. Our results show that autodoping is linearly dependent on the substrate doping concentration and becomes significant when the arsenic concentration is greater than
2×1018 cm−3
. The autodoping can be reduced by a factor of about five by masking the back of the substrate with silicon oxide or by heating the substrate at a high temperature for a few minutes to allow the arsenic near the back surface to evaporate prior to deposition.