“…Thus, the two-phase model of recrystallization is an initial-boundary value problem ( 1), ( 24)- (28). The detail analysis we hold in [33] in the case of the problem of the second type.…”
Section: Problem Formulationmentioning
confidence: 99%
“…Of interest is a theoretical description of the regularities of recrystallization at various boundary regimes [24,25,26] for controlling the fluxes of impurities from the coating to the sample [27,28,29]. In the present paper, we describe the peculiarities of recrystallization kinetics activated by diffusion taking into account the impurity exchange between the polycrystalline and the coating.…”
Two models of recrystallization are proposed taking into account the convective flux of impurity exchange between the polycrystalline and the thin-film coating. The special boundary modes of recrystallization described by the single-phase and two-phase Stefan problems with the boundary condition at coated surface containing the convective term. The exact solutions of the formulated problems corresponding to the grain-boundary concentration of impurities are obtained. The detail theoretical analysis focused on the third type problem shows that the concentration of impurities and the width of the recrystallized layer increase with an increase in the annealing time. An increase in intensity of impurity exchange between the polycrystalline and the coating promotes an increase in the width of the recrystallized layer. The recrystallization front position increases with an increase in the surface concentration of impurities and it decreases with an increase in the intensity of the impurity flux from the surface. The rate of recrystallization kinetics increases with an increase in the intensity of impurity exchange between the polycrystalline and the coating
“…Thus, the two-phase model of recrystallization is an initial-boundary value problem ( 1), ( 24)- (28). The detail analysis we hold in [33] in the case of the problem of the second type.…”
Section: Problem Formulationmentioning
confidence: 99%
“…Of interest is a theoretical description of the regularities of recrystallization at various boundary regimes [24,25,26] for controlling the fluxes of impurities from the coating to the sample [27,28,29]. In the present paper, we describe the peculiarities of recrystallization kinetics activated by diffusion taking into account the impurity exchange between the polycrystalline and the coating.…”
Two models of recrystallization are proposed taking into account the convective flux of impurity exchange between the polycrystalline and the thin-film coating. The special boundary modes of recrystallization described by the single-phase and two-phase Stefan problems with the boundary condition at coated surface containing the convective term. The exact solutions of the formulated problems corresponding to the grain-boundary concentration of impurities are obtained. The detail theoretical analysis focused on the third type problem shows that the concentration of impurities and the width of the recrystallized layer increase with an increase in the annealing time. An increase in intensity of impurity exchange between the polycrystalline and the coating promotes an increase in the width of the recrystallized layer. The recrystallization front position increases with an increase in the surface concentration of impurities and it decreases with an increase in the intensity of the impurity flux from the surface. The rate of recrystallization kinetics increases with an increase in the intensity of impurity exchange between the polycrystalline and the coating
The model of diffusional mass transfer in the medium with a strong spatial dependence of diffusivity and its application to the grain boundary (GB) diffusion problem is presented. A significant decrease of diffusion activation energy is shown to take place takes place in the vicinity of non-equilibrium grain boundary, which leads to the formation of a region of enhanced diffusion. The generalization of grain boundary diffusion theory is given which accounts for the diffusion enhancement near GB. An original mathematical approach is developed and general asymptotic solutions of the one-and two-dimensional diffusion problems are derived for two types of diffusant source — constant and instant. The applicability domain of presented model is discussed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.