Der Faktor der inneren Umwandlung beim 40 keV-�bergang des 81 208 T1

Krause, I. Y.

doi:10.1007/bf01344216

Cited by 6 publications

(1 citation statement)

References 18 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…We found a few structure prototypes that fulfil the four Pauling rules: the rutile structure type, for example, SnO 2 (mp‐856), spinels such as MgAl 2 O 4 (mp‐3536), structures in the scheelite structure type (CaWO 4 ) such as BiAsO 4 (mp‐561068), and many structures in the ZrSiO 4 (mp‐4820) structure type. Furthermore, some phosphates such as α‐AlPO 4 (mp‐3955, berlinite), which is isotypic to α‐quartz, several sulfates such as In 2 (SO 4 ) 3 (mp‐541450), and silicates such as Mg 2 SiO 4 (mp‐2895) are among the fulfilling structures. If one looks at the elementwise fulfilment of these four rules in Figure b, one can see that structures including Al and Si tend to fulfil the rule better than structures including P and the alkali and alkaline‐earth metals.…”

Section: Resultsmentioning

confidence: 99%

The Limited Predictive Power of the Pauling Rules

et al. 2020

View full text Add to dashboard Cite

The Pauling rules have been used for decades to rationalise the crystal structures of ionic compounds. Despite their importance, there has been no statistical assessment of the performances of these five empirical rules so far. Here, we rigorously and automatically test all five Pauling rules for a large data set of around 5000 known oxides. We discuss each Pauling rule separately, stressing their limits and range of application in terms of chemistries and structures. We conclude that only 13 % of the oxides simultaneously satisfy the last four rules, indicating a much lower predictive power than expected.

show abstract

Section: Resultsmentioning

confidence: 99%