Depositional environment of Middle Triassic organic‐rich shales in the Ordos Basin, Northwest China

Abstract

The Middle Triassic Tongchuan Formation in the Ordos Basin of northwestern China is a typical lacustrine deposit. A major component of this formation is thick layers of organic‐rich shales that are probably a potential hydrocarbon source and preserve the earliest known Mesozoic‐type lacustrine ecosystem. The exact depositional environment of the shales in the Tongchuan Formation, however, remains unknown. To address this question, we carried out high‐resolution carbon (δ13Corg) and sulphur (δ34Spy) isotope analysis as well as undertook total organic carbon (TOC)/pyrite contents and pyrite morphology investigation, and framboidal pyrite size measurements in shales of the Bawangzhuang section of the southern Ordos Basin. Remarkably high TOC (23 ± 9%) and pyrite (7 ± 3%) contents were obtained from the shales, which indicate a large amount of organic carbon and pyrite burial during shale deposition. Framboids are the dominant pyrite morphology in the pyrite crystals and show large and variable mean diameters (7.0 ± 1.7 μm to 14.3 ± 6.8 μm) across the section, indicating oxic–dysoxic bottom water during shale deposition. δ13Corg and δ34Spy revealed narrow and less variable values, ranging from −31.8‰ to −28.1‰, and −4.1‰ to 4.9‰, respectively. The δ13Corg values suggest balanced and consistent carbon cycles. Integrated with pyrite content and morphological patterns, consistent δ34Spy values probably demonstrate a relatively open environment for the formation of sedimentary pyrite, and thus a shallow chemocline that was quite close to the water‐to‐sediment interface during shale deposition. Overall, the organic‐rich shales of the Tongchuan Formation were probably deposited under oxic–dysoxic bottom‐water conditions. Shallow chemocline depth combined with moderately high sedimentation rate and high primary productivity may have played crucial roles in the deposition and formation of the organic‐rich shales in the Tongchuan Formation. The shallow chemocline also facilitates the fossil preservation in a lacustrine environment.

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Mercury evidence of Deccan volcanism driving the Latest Maastrichtian warming event

“…We conducted geochemical analyses of δ 13 Corg and total organic carbon (TOC) content, and δ 13 Ccarb at the Nanjing Institute of Geology and Palaeontology, Chinese Academy of Sciences. Methods of analyses of δ 13 Corg and TOC are referred to Zhao et al (2021). Methods of analyses of δ 13 Ccarb are referred to Yu et al (2018).…”