A B S T R A C TMagnetic carbon nanocomposites were prepared from maize wastes and were characterized by surface area analyzer, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric/differential thermal analysis (TG/DTA), and electron dispersive X-ray (EDX). The presence of iron oxide on the adsorbent surface was confirmed from SEM, XRD, and FT-IR analysis. Freundlich and Langmuir isotherms were used for the determination of adsorption parameters. The effect of pH on adsorption process was evaluated, and a decline in percent adsorption was noted at high pH. The equilibrium time at pH 7 and 3 was 96 and 180 min, respectively, and nearly 90% removal of aflatoxin B1 was achieved for both adsorbent. Pseudo-first-order and pseudosecond-order kinetic equations were used to analyze the kinetic data. Best fit was obtained with pseudo-first-order kinetics equation. The thermodynamics parameters were also determined, ΔS˚was positive (64.438 kJ mol −1 deg −1 ) while ΔH˚(−16.24 kJ mol −1 ) and ΔG˚were negative (−1.949, −2.593, −3.238, and -3.882 kJ mol −1 corresponding to 30, 40, 50, and 60˚C, respectively).