Deposit Probe Measurements in Large Biomass-Fired Grate Boilers and Pulverized-Fuel Boilers

Abstract

A number of full-scale deposit probe measuring campaigns conducted in grate-fired and suspension-fired boilers, fired with biomass, have been reviewed and compared. The influence of operational parameters on the chemistry of ash and deposits, on deposit build-up rates, and on shedding behavior has been examined. The firing technology and the fuel utilized influence the fly ash and deposit chemical composition. In grate-firing, K, Cl, and S are enriched in the fly ash compared to the fuel ash, while the fly ash in suspension-firing is relatively similar to the fuel ash. The chemical composition of the deposits formed is determined by the fly ash composition and the flue gas temperature; increases in the local flue gas temperature lead to higher contents of Si and Ca and lower contents of Cl in the deposits. The net deposit build-up rates in grate-fired and suspension-fired boilers are at similar levels, 0–100 g/m2·h, while the ash deposit propensity is an order of magnitude larger in grate fired boilers than in suspension-fired boilers. Deposit build-up rates were found to increase at flue gas temperatures close to the melting temperatures of the fly ash. Furthermore, the rate of deposit build-up increased with the K-content of the fuel ash and fly ash for grate-fired boilers. For suspension-fired boilers, deposition rates are comparatively low for wood-firing and increase with increasing fuel straw shares. Shedding of deposits occurs by melting during straw-firing on a grate at high flue gas temperatures (>900 °C). At lower flue gas temperatures, the deposits can be removed by soot blowing. The required soot blower impact pressure is strongly influenced by the surface temperature, such that a high surface temperature makes the deposit more difficult to remove. During straw/wood-firing in suspension-fired boilers, shedding occurred by debonding with incomplete removal at flue gas temperatures of 600–1000 °C and by debonding with complete removal during wood-firing in suspension-fired boilers at high flue gas temperatures (1300 °C). Shedding events were not observed during wood suspension-firing at low flue gas temperatures (<900 °C). Here, a steady-state mass of deposits on the probe was observed. Increased exposure times and probe temperatures lead to deposits that are difficult to remove. This was observed for grate-firing of straw and for straw/wood firing in suspension-fired boilers.

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Potassium Capture by Kaolin, Part 2: K2CO3, KCl, and K2SO4

“…Potassium is present naturally in plant materials and it is the main cause for most ash-related problems, [3][4][5][6] including deposition, 7-10 corrosion 11,12 and SCR catalyst deactivation in biomass-fired boilers. [13][14][15] During biomass combustion, potassium is released to gas phase in different forms depending on the ash chemistry of the fuels and combustion conditions.…”

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“…Combustion of biomass for power production results in the deposition of corrosive K, Cl and S rich species on the superheater tubes [1,2]. These species aggravate fast corrosion of the superheaters at higher temperatures [3].…”