Dephosphorization of Oolitic Goethite Iron Ore by Roasting-Leaching Process

Abstract

Oolitic iron ores have significant economical importance because of their extensive resources in the world. However, their utilisation is often quite limited due to the high content of phosphorus inside. The phosphorus is often finely disseminated in the oolite structure and generally not liberated in the form of free particles. The iron ore used in this work is a typical oolitic goethitic iron ore with high phosphorus. The process of phosphorus removal from this ore is difficult because the phosphorus is not present as distinct minerals. As a result, no physical beneficiation process is able to separate the phosphorus from the iron bearing phases. The current concentrate contains low iron grade (Fe ~49%) and high phosphorus content (P 0.7~0.8%). The acid leaching is a potential way to dissolve phosphorus. Previous studies have shown that the thermal treatment makes the phosphorus more accessible for the acids and enables more efficient phosphorus dissolution. Some chemical additives are reported to enhance this phenomenon. A series of tests have been carried out using roasting -grinding -magnetic separation -leaching technologies to remove the phosphorus from this current concentrate. In the first stage, several tests were performed at pilot scale under the same conditions as described in some publications. The achieved results were similar to those from previous tests at laboratory scale. In the second stage, new test conditions were investigated in laboratory scale in order to achieve better result and to reduce the operational cost.