“…33 Metal oxides (such as Al 2 O 3 , TiO 2 , CeO 2 and ZrO 2 ) are recognized as proper HDO supports due to their acidity. 5,[34][35][36] It is worth noting that a certain amount of water can be produced during the HDO reaction, which will be adsorbed on these hydrophilic supports and occupy some active sites, thus decreasing the catalytic activity. Therefore, the hydrophobicity of the catalyst remains to be improved.…”
Aqueous-phase hydrodeoxygenation (HDO) of biomass-derived phenolic compounds is considered as one of the most promising ways to convert biomass into fuels and value-added chemicals. The aim of this study is...
“…33 Metal oxides (such as Al 2 O 3 , TiO 2 , CeO 2 and ZrO 2 ) are recognized as proper HDO supports due to their acidity. 5,[34][35][36] It is worth noting that a certain amount of water can be produced during the HDO reaction, which will be adsorbed on these hydrophilic supports and occupy some active sites, thus decreasing the catalytic activity. Therefore, the hydrophobicity of the catalyst remains to be improved.…”
Aqueous-phase hydrodeoxygenation (HDO) of biomass-derived phenolic compounds is considered as one of the most promising ways to convert biomass into fuels and value-added chemicals. The aim of this study is...
“…nickel, zinc, molybdenum, and cobalt have also received special focus due to their immense potential for deep deoxygenation with minimum hydrogen consumption and carbon loss. [14][15][16][17][18] For instance, fast pyrolysis of lignin over cobalt oxide embedded on HZSM-5 provided it with decent catalytic behavior for direct deoxygenation of lignin. 19 Besides, cobalt nitride supported on nitrogen-doped carbon has been quite promising for hydrodeoxygenation (HDO) of lignin-derived phenols under mild conditions.…”
In this study, Kraft lignin-derived bio-oil was upgraded with LiCoO2 or Co3O4-impregnated hierarchical nano-ZSM-5 catalysts. The synthesized catalysts were characterized by N2-Ads-Des, XRD, XPS, NH3-TPD, FTIR, FESEM and ICP-OES. Upon...
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