Density of a Thorium Monolayer for Maximum Thermionic Emission

Abstract

An investigation is described in which a high-sensitivity analytical balance of standard design is used for determination of the surface density of that thorium layer which corresponds to maximum thermionic emission with the thorium-on-tungsten system. Following Brattain and Becker's definition of this value of surface density as one ``f unit,'' thorium vapor is allowed to accumulate on a quartz plate until a weighable number of f units (about 600) has been deposited. The thorium flux in f units per minute is monitored periodically by means of a tungsten filament diode during the course of the deposition. Two polycrystalline specimens of ribbon from the same source have yielded the value of (4.2±0.2)1014 atoms/cm2 as the density for maximum emission. This is to be compared with a value of 5.0×1014 atoms/cm2 obtained in 1934 on theoretical grounds by Langmuir.

Critical Phenomena with Thorium Adsorbed on Single Crystal Tungsten

“…A monolayer of adsorbed HCOOH molecules does not occupy (9) the surface area which is available to hydrogen adsorption in the absence of formic acid. This fact suggests a participation of the net reaction of hydrogen evolution 2H + d-2e-~ H2 [3] and of the Volmer reaction…”

“…For further information on the general experimental procedure and the method of calibrating the second ribbon see ref. (1) and (3).…”