2023
DOI: 10.1002/adem.202370001
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Density‐Dependent Impact Resilience and Auxeticity of Elastomeric Polyurea Foams

Abstract: Impact resilient elastomeric polyurea foams are shown to absorb more than 50% of the incoming impact energy even after several impact events, making these foams especially useful in sports and biomechanics applications. This superior impact energy absorption capacity originates from the symbiotic contributions of the hyper‐viscoelastic behavior of the base polyurea, the microstructural features, and cell architecture. Further details can be found in the article number http://doi.wiley.com/10.1002/adem.20220057… Show more

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“…Namely the former is classified as semiclosed cells with perforations and microsphere reinforcements, while the latter is closed cells with nearly uniform diameters. [ 5,21,22,33,34 ] Notably, the dynamic stress–strain curves of polyurea foams reveal rapid transition into the plateau region, delayed densification that further extended the plateau region, and enhanced the overall dynamic performance. An elaborative discussion about the difference between the dynamic and quasistatic behavior of conventional and density‐graded polyurea foams is included in forthcoming reports by this group.…”
Section: Resultsmentioning
confidence: 99%
“…Namely the former is classified as semiclosed cells with perforations and microsphere reinforcements, while the latter is closed cells with nearly uniform diameters. [ 5,21,22,33,34 ] Notably, the dynamic stress–strain curves of polyurea foams reveal rapid transition into the plateau region, delayed densification that further extended the plateau region, and enhanced the overall dynamic performance. An elaborative discussion about the difference between the dynamic and quasistatic behavior of conventional and density‐graded polyurea foams is included in forthcoming reports by this group.…”
Section: Resultsmentioning
confidence: 99%
“…That is, the initial negative Poisson's ratios tend to vary substantially during large deformation loading events, often starting at a negative value and approaching zero or even positive (non-auxetic) values at larger strains. Evidence for such strongly strain-dependent auxetic response has been reported for elastomeric foams and additively manufactured cellular structures [10][11][12][13], noting that an uncontrollable Poisson effect can adversely affect the performance and the sought application of the auxetic structures.…”
Section: Introductionmentioning
confidence: 97%