Density measurements were carried out for aqueous solutions of the ionic liquids [BMIm]Cl, [BMIm]Br, [BMIm][BF 4 ], [HMIm]Br, [OMIm]Br, [MMIm][MSO 4 ], and [EMIm][ESO 4 ] at T = (288.15−318.15) K.The measured densities were used to compute the standard partial molar volumes (V ϕ 0 ) of the ILs using Redlich−Mayer and Pitzer equations. The results show that the V ϕ 0 values obtained from both equations are fully compatible and that the difference is less than 0.5 cm 3 •mol −1 for all the ionic liquids. The first derivative of V ϕ 0 with respect to temperature give the values of partial molar expansivity (E ϕ 0 ), and its second derivative with respect to temperature provided Hepler's constant ((∂ 2 V ϕ 0 /∂T 2 ) P ) an important parameter to discuss the structure-making or -breaking tendency of the ILs in aqueous solutions. The values of (∂ 2 V ϕ 0 /∂T 2 ) P for all the ILs except for [OMIm]Br were found to be negative, showing that these ILs behave as structure breakers in aqueous media.