Densities and refractive indices for binary and ternary mixtures of (carbon tetrachloride + β-pinene + 2-chlorobutane) at T = 298.15 K

Rezaei–Sameti, M.; Khanlarzadeh, Khatereh; Iloukhani, H.

doi:10.1007/s00706-013-0958-y

Cited by 6 publications

(4 citation statements)

References 13 publications

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“…The excess molar volumes (a thermodynamic quantity) of the binary systems were calculated from the density measurements of the pure components and their mixtures using the following equation − M 1 and M 2 are the molar masses and d 1 and d 2 are the densities of liquids 1 and 2, respectively.…”

Section: Resultsmentioning

confidence: 99%

“…The values of the excess molar volume of (heavy alcohols + CPO) are positive throughout the entire composition range (Figure c) due to several effects. These effects are caused by the addition of the dipolar aprotic molecules (cyclic ketone), which break the molecular self-association of the constituent molecules, the declustering, and steric hindrance. , The positive value of V̅ E suggests the formation of a less compact packing of the solution structure compared to the constituent liquids.…”

Section: Resultsmentioning

confidence: 99%

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Permittivities, Refractive Indices, Densities, and Excess Properties for Binary Systems Containing 1-Alkanols and Cyclopentanone

Gilani

Ramezani

2018

J. Chem. Eng. Data

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This study reports the experimental relative permittivity, refractive index, and density data for several polar binary systems containing a cyclic ketone (cyclopentanone) and a series of alkanols from C 2 to C 10 over the entire composition range at T = 298.15 and p = 101.3 kPa. Further study was performed on a polar−nonpolar system composed of cyclopentanone and cyclohexane at the mentioned temperature and pressure. The experimental data were analyzed with various approaches in a consistence framework and in terms of intermolecular interactions between the constituent molecules. The effective and corrective Kirkwood correlation factors were calculated, in order to investigate the H-bond structure formation in the mixtures. The intermolecular interactions were investigated through various excess parameters, namely, excess permittivity, excess refractive index, excess molar volumes, excess Helmholtz energies, and excess Kirkwood correlation factors.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Permittivities, Refractive Indices, Densities, and Excess Properties for Binary Systems Containing 1-Alkanols and Cyclopentanone

Gilani

Ramezani

2018

J. Chem. Eng. Data

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“…Various kinds of specific (hydrogen bond formation), nonspecific (the dipole–dipole and dispersion forces) interactions and structural (geometrical) changes in a mixture may contribute in some extent to the ̅ E quantities. The structural change is due to differences in the size and shape of the heteromolecules in the mixtures …”

Section: Results and Discussionmentioning

confidence: 99%

“…The structural change is due to differences in the size and shape of the heteromolecules in the mixtures. 84 The corresponding data for the excess molar volume of the (CPO or CHO + pentanols) systems are given in Supporting Information Tables S3 and S4. As shown in Figure 9c,f, the V m E values are positive for the {(CPO or CHO + primary and secondary pentanols (1-PA, 2-PA, 3-PA, IPA)} systems over the full composition range at 298.15 K. The positive sign of V m E can be due to the formation of a less compact packing of the mixture structure compared to the constituent liquids.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

Dielectric, Volumetric, Refractometric, and Excess Properties of (Cycloalkanone + Pentanol Isomers) Systems at T = 298.15 K

Gilani

Mirkhalili

2021

J. Chem. Eng. Data

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Relative permittivity, refractive index, and density data were experimentally determined for several binary systems (cyclopentanone or cyclohexanone + pentanol isomers) over the entire composition range at 298.15 K and 101.3 kPa for the first time. The selected pentanol isomers were 1-pentanol, 2-pentanol, 3-pentanol, isopentanol, and tert-pentanol. The experimental physicochemical data were used to calculate the various excess quantities. These quantities were applied to interpret the manner of cycloalkanone−pentanol interactions. Excluding the mixtures containing tertiary pentanol, the excess permittivities were found to be negative for all the studied systems. The mixtures containing the weakly associated tert-pentanol display a reverse physicochemical and excess behavior when compared to the systems containing the strongly associated primary and secondary pentanols. The Redlich−Kister equation was used to fit the experimental excess molar volumes. For the studied systems, a negative correlation exists between the excess molar volume (V̅ E ) and excess refractive index (n E ).

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Refractive index of β-pinene

Wohlfarth¹

2017

Optical Constants

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Densities and refractive indices for binary and ternary mixtures of (carbon tetrachloride + β-pinene + 2-chlorobutane) at T = 298.15 K

Cited by 6 publications

References 13 publications

Permittivities, Refractive Indices, Densities, and Excess Properties for Binary Systems Containing 1-Alkanols and Cyclopentanone

Permittivities, Refractive Indices, Densities, and Excess Properties for Binary Systems Containing 1-Alkanols and Cyclopentanone

Dielectric, Volumetric, Refractometric, and Excess Properties of (Cycloalkanone + Pentanol Isomers) Systems at T = 298.15 K

Refractive index of β-pinene

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