1998
DOI: 10.1006/jcht.1997.0334
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Densities and excess molar volumes of the solvent (ethane-1,2-diol + 2-methoxyethanol + water) fromT=263.15 K toT=353.15 K

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Cited by 11 publications
(4 citation statements)
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“…This behaviour may be explained by the relative energetically favourable rotameric conformers[10,25] (anti and gauche). The observed V E m values suggest a stronger interaction in the system 2-methoxyethanol with 2-propanol than in that containing 1-propanol.…”
mentioning
confidence: 96%
“…This behaviour may be explained by the relative energetically favourable rotameric conformers[10,25] (anti and gauche). The observed V E m values suggest a stronger interaction in the system 2-methoxyethanol with 2-propanol than in that containing 1-propanol.…”
mentioning
confidence: 96%
“…In fact, the excess molar volume V E m > 0 at all experimental conditions, (17) while the excess refractive index (figure 2) is negative. By combining these opposite behaviours into the R E property, we observe a predominance of the V E m contribution at low temperatures, an offset of the two effects around T = 323 K, and an obvious predominance of the n D contribution at high temperatures.…”
Section: {Dce (1) + Ce (2)} Has Been Calculated From the Refractive Imentioning
confidence: 90%
“…where ρ is the liquid density, (17) ε 0 is the relative permittivity of vacuum, and ε and ε ∞ are the static (taken from reference 7) and high-frequency permittivities of the mixtures, respectively. For the latter the value ε ∞ ≈ 1.1·n 2 D was used, according to literature suggestions.…”
Section: The Kirkwood Correlation Parametermentioning
confidence: 99%
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