Densification Behavior and Dielectric Properties of CaO-B&lt;sub&gt;2&lt;/sub&gt;O&lt;sub&gt;3&lt;/sub&gt;-SiO&lt;sub&gt;2&lt;/sub&gt; System Glass-Ceramics Containing ZrO&lt;sub&gt;2&lt;/sub&gt;

Liu, Jin Zhuang; Yao, Zhonghua; Xu, Nuo; Zhang, Qi Long; Yang, Hui

doi:10.4028/www.scientific.net/kem.697.253

Cited by 6 publications

(2 citation statements)

References 12 publications

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“…According to He et al., ZrO 2 negatively affects the dielectric properties of calcium borosilicate glass‐ceramics by disrupting the glass structure 170 . Contradictorily, a second investigation into the calcium borosilicate glass‐ceramic system shows that added ZrO 2 will improve the densification, crystallization, and ultimately dielectric properties 171 . Other studies regarding electrical applications include zirconia in their glass‐ceramic compositions but do not specifically address the effect of zirconia 172,173 .…”

Section: Applications Of Zro2 Added Glass‐ceramicsmentioning

confidence: 99%

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Shearer,

Montazerian,

Deng

et al. 2024

Int J Ceramic Engine & Sci

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This article reviews promising studies on the design, manufacturing, microstructure, properties, and applications of glass‐ceramics containing ZrO2 and relevant glass‐ceramic matrix composites. After the addition of ZrO2 to a glass‐ceramic composition, it can persist in the residual glassy phase, facilitate nucleation, and/or precipitate as ZrO2 or another zirconate crystalline phase. Also, ZrO2‐reinforced or ZrO2‐toughened glass‐ceramics can be designed as composites. In this article, the term “ZrO2‐containing glass‐ceramics” encompasses all these scenarios in which ZrO2 is present. Such glass‐ceramics offer a wide range of applications in modern industries, including but not limited to architecture, optics, dentistry, medicine, and energy. Since S. Donald Stookey's discovery of glass‐ceramics in the early 1950s, the most important scientific efforts reported in the literature are reviewed. ZrO2 is commonly added to glass‐ceramics to promote nucleation. As a result, the role of ZrO2 in structural modification of residual glass and stimulating the nucleation in glass‐ceramic is first discussed. ZrO2 can also be designed into the main crystalline phase of glass‐ceramics, contributing achieving super high fracture toughness above 4 MPa·m0.5. Experimental and computational studies are reviewed in detail to elucidate how the transformation toughening and other mechanisms help to achieve such high values of fracture toughness. Sintered and glass‐ceramic matrix composites also show promise, where ZrO2 contributes to improved stability and mechanical properties. Finally, we hope this article will provoke interest in glass‐ceramic materials in both the scientific and industrial communities so that their tremendous technological potential in developing, for example, tough, thermally stable, transparent, and biologically compatible materials can be realized more widely.

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Section: Applications Of Zro2 Added Glass‐ceramicsmentioning

confidence: 99%

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Shearer,

Montazerian,

Deng

et al. 2024

Int J Ceramic Engine & Sci

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“…Glass ceramics have become a new kind of structural and functional material because of their excellent properties, which have attracted the attention of researchers [1][2][3][4][5][6][7]. Glass ceramics can be produced by melting glass and converting it into a glass ceramic by an appropriate heat treatment, which should cause the devitrification of the glass and the uniform nucleation and growth of fine crystals during bulk crystallization [8][9][10].…”

Section: Introductionmentioning

confidence: 99%

Preparation and Characterization of Na2O-Y2O3-P2O5-SiO2 Transparent Glass Ceramics

Zhao

Zou

Wei

et al. 2018

SSP

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Transparent glass ceramics containing Na3.6Y1.8(PO4)3 crystals were successfully synthesized using high temperature melting quenching and subsequent heat treatment of the precursor glass with a composition 15Na2CO3-3Y2O3-45SiO2-31H3BO3- 5.4P2O5-0.6Sb2O3 (mol%). The impact of heat treatment is investigated in detail. The glass sample was tested by differential scanning calorimetry analysis to determine the heat treatment system. The ideal heat-treated condition is at 650°C for 2 h. The structure and morphology properties were systematically analyzed by recording X-ray diffraction patterns and scanning electron microscopy images, which indicate that Na3.6Y1.8(PO4)3 crystal were precipitated homogeneously among the glass matrix. The microstructural of precursor glass and glass ceramic were compared by analyzing FTIR spectra, indicating the formation of phosphate groups in glass ceramic. The refractive index of glass ceramics samples were measured. In the visible region, the transmittance of glass ceramics is up to 85%. Moreover, the relationship between the refractive index of the sample and the transmittance is discussed.

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Crystallization behaviour and properties of BaO-CaO-B 2 O 3 -SiO 2 glasses and glass-ceramics for LTCC applications

Zhu

Agathopoulos

et al. 2018

Ceramics International

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Densification Behavior and Dielectric Properties of CaO-B<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> System Glass-Ceramics Containing ZrO<sub>2</sub>

Cited by 6 publications

References 12 publications

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Zirconia‐containing glass‐ceramics: From nucleating agent to primary crystalline phase

Preparation and Characterization of Na<sub>2</sub>O-Y<sub>2</sub>O<sub>3</sub>-P<sub>2</sub>O<sub>5</sub>-SiO<sub>2</sub> Transparent Glass Ceramics

Crystallization behaviour and properties of BaO-CaO-B 2 O 3 -SiO 2 glasses and glass-ceramics for LTCC applications

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