The synthesis and characterisation of a new type of porphyrin-based tetrakis(Hamilton receptor) 1 is presented and the complexation of 1 with the chiral depsipeptide dendrons 7-12, with cyanuric acid functionalities as their focal points, is reported. The resulting first-to third-generation chiral supramolecular dendrimers 13-18 were characterised by NMR, UV/Vis and CD spectroscopy. Chirality transfer from the depsipeptide dendrons to the porphyrin core was demonstrated by CD spectroscopy in the case of the second-and third-generation complexes 15-18, whereas no chirality transfer and hence no diastereoselective formation of a chiral superstructure could be determined in the case of the first-generation systems. The intensities of the complexes' CD absorptions in