2018
DOI: 10.3390/met8110924
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Dendritic Segregation of Zn-Al Eutectoid Alloys

Abstract: The structural investigations performed and described in this paper are focused on both the segregation phenomenon at the dendrite level, and on the external structure in the equilibrium state. Qualitative and quantitative investigations of the Zn-Al eutectoid alloy (22% Al) structures in equilibrium and non-equilibrium states were considered and studied, revealing that, in this composition, dendritic segregation determines the eutectic transformation. Solidification in non-equilibrium conditions controls both… Show more

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Cited by 9 publications
(3 citation statements)
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“…In general, it was understood that different eutectoid transformations took place at different cooling rates and consequently the formation of a different microstructure. Therefore, it is possible that the amount of critical fluid in the microstructure may vary as a result of off-balance solidification, which leads to a different solid-liquid interface [40]. As a result, at high cooling rates, due to rapid solidification, the shrinkage is trapped in the casting, and at slow cooling speeds the porosity is shifted towards the mold top region.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…In general, it was understood that different eutectoid transformations took place at different cooling rates and consequently the formation of a different microstructure. Therefore, it is possible that the amount of critical fluid in the microstructure may vary as a result of off-balance solidification, which leads to a different solid-liquid interface [40]. As a result, at high cooling rates, due to rapid solidification, the shrinkage is trapped in the casting, and at slow cooling speeds the porosity is shifted towards the mold top region.…”
Section: Resultsmentioning
confidence: 99%
“…They found that the conditions that cause phase separation during eutectic and eutectoid transformation will determine the structural modifications of the alloy when the Al segregation occurs at the dendrite level. In addition, using thermal analysis, they found that the phase transformation temperatures and microstructure changes due to different cooling rates [40]. The cooling rate of the molten zinc is determined by the balance of thermal energy released from melt to mold wall [44].…”
Section: Resultsmentioning
confidence: 99%
“…This may be due to the phenomenon of grain boundary segregation that occurs in the alloys during the extrusion process, resulting in the accumulation of Al elements at the grain boundaries. This phenomenon may have a negative impact on the mechanical properties of the alloy [29,32].…”
Section: Microstructure Of Alloys In the Extruded Statementioning
confidence: 99%