Dendritic fibrous nanosilica-supported dendritic IL/Ru(ii) as photocatalysts for the dicarbofunctionalization of styrenes with carbon dioxide and amines

Abstract

The effectual utilization of heterogeneous catalysts from nano sources through chemical moderation for the α-aminomethylcarboxylation of alkenes with carbon dioxide and amines is an attractive area to study.

The Capture and Catalytic Conversion of CO2 by Dendritic Mesoporous Silica‐Based Nanoparticles

“…Others can be found in the followings. [99,107,108,120] In summary, specifically selecting, rationally designing, and elaborately constructing DMSNs-based catalysts could successfully convert CO 2 into value-added organic compounds.…”

“…designed a series of imidazole‐based ionic liquids to anchor Ru(II) (㉔–㉖ in Figure S3, Supporting Information), and the resultant DMSNs‐IL‐Ru(II) owned high catalytic activity for α‐aminomethyl carboxylation of alkenes with CO 2 and amines (Scheme 16). [ 120 ] Very recently, Li et al. immobilized Ru NPs onto an IL‐functionalized DMSNs heterogeneous catalyst (Figure S4, Supporting Information) for hydroformylation of alkenes with CO 2 and H 2 (Scheme 17).…”

“…[119] Liu et al designed a series of imidazole-based ionic liquids to anchor Ru (II) (㉔-㉖ in Figure S3, Supporting Information), and the resultant DMSNs-IL-Ru(II) owned high catalytic activity for αaminomethyl carboxylation of alkenes with CO 2 and amines (Scheme 16). [120] Very recently, Li et al immobilized Ru NPs onto an IL-functionalized DMSNs heterogeneous catalyst (Figure S4, Supporting Information) for hydroformylation of alkenes with CO 2 and H 2 (Scheme 17). [121] Even though the catalytic activity and the recyclability of the as-prepared DMSNs-IL-Rh were satisfactory, the selectivity of the n-phenylpropyl and iso-phenylpropyl aldehyde was not probed into.…”

Visible Light Induced Three‐Component 1,2‐Dicarbofunctionalization of Alkenes and Alkynes

“…Another important work was reported by Rouhi and co‐workers [59] in 2021, where a CO 2 ‐assisted dicarbofunctionalization of styrene derivative to result in γ‐amino acid 46 c was achieved and the yield was as high as 97 % (Scheme 46). They used DFNS/IL/Ru catalyst under the irradiation of visible light to couple N , N ‐dimethylaniline 46 b , a substituted styrene 46 a and CO 2 in acetonitrile‐triethanolamine mixture solvent.…”

Enhanced visible light photocatalytic activity of octopod Ag3PO4 microcrystals with high index crystal faces

“…1–4 Compared with other traditional methods, semiconductor photocatalysis technology has the advantages of simple, recyclability, and high efficiency, and is used widely for antibacterial, deodorization, self-cleaning etc. 5–8…”