The democracy-science relationship has traditionally been examined through philosophical conjecture and country case studies. There remains limited global-scale empirical research on the topic. This study explores country-level factors related to the dynamics of the global research collaboration network, focusing on structural associations between democratic governance and the strength of international research collaboration ties. This study combines longitudinal data on 170 countries between 2008 and 2017 from the Varieties of Democracy Institute, World Bank Indicators, Scopus, and Web of Science bibliometric data. Methods include descriptive network analysis, temporal exponential random graph models (TERGM), and valued exponential random graph models (VERGM). The results suggest significant positive effects of democratic governance on the formation and strength of international research collaboration ties and homophily between countries with similar levels of democratic governance. The results also show the importance of exogenous factors, such as GDP, population size, and geographical distance, as well as endogenous network factors, including preferential attachment and transitivity.