2009
DOI: 10.1002/jrs.2459
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Della Robbia blue glaze: micro‐Raman temperature study and X‐ray fluorescence spectroscopy characterization

Abstract: Micro-Raman temperature study and X-ray fluorescence (XRF) spectroscopy were used for characterization of the blue glaze on Saint Johnthe Baptist -majolica terracotta relief attributed to Andrea Della Robbia and Saint Johnthe Baptist withCross -majolica terracotta statue attributed to Giovanni Della Robbia. Both objects are on permanent exhibition in the John and Mable Ringling Museum of Art in Sarasota, FL. This study proves that the detection of the 548 cm −1 Raman band alone cannot serve as evidence for pre… Show more

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Cited by 12 publications
(8 citation statements)
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“…Micro‐Raman temperature studies and X‐ray fluorescence (XRF) spectroscopy were used by Sendova et al . for the characterization of the blue glaze on Saint John the Baptist‐majolica terra cotta relief, attributed to Andrea Della Robbia, and Saint John the Baptist with Cross, a majolica terra cotta statue, attributed to Giovanni Della Robbia . It was proposed that the Della Robbia family used Co‐containing sulfide ores as a source for manufacturing their blue pigments.…”
Section: Art and Archeologymentioning
confidence: 99%
“…Micro‐Raman temperature studies and X‐ray fluorescence (XRF) spectroscopy were used by Sendova et al . for the characterization of the blue glaze on Saint John the Baptist‐majolica terra cotta relief, attributed to Andrea Della Robbia, and Saint John the Baptist with Cross, a majolica terra cotta statue, attributed to Giovanni Della Robbia . It was proposed that the Della Robbia family used Co‐containing sulfide ores as a source for manufacturing their blue pigments.…”
Section: Art and Archeologymentioning
confidence: 99%
“…The resonance Raman spectrum of the vibrations associated to the lazurite chromophores S 3 − and S 2 − ions under green laser excitation demonstrated the presence of ultramarine in Mamluk‐enamelled precious objects (Colomban et al). According to Sendova et al, the chromophores evidenced by Raman spectroscopy in some ‘Della Robbia’ blue glazes, arose from the thermal treatment of the used raw materials from Co‐containing sulphide ores and not from lapis lazuli incorporation. The unicity of this finding has been questioned by Colomban …”
Section: Introductionmentioning
confidence: 99%
“…Furthermore, specific studies regarding Modern Art paintings have been conducted for the works of Francis Picabia [9], Pablo Picasso and Jasper Johns [10]. Scanning electron microscopy coupled with energy dispersive X-ray spectrometry (SEM/EDS) could be useful for obtaining complementary information about the raw materials used in the artifacts [16,17].…”
Section: Introductionmentioning
confidence: 99%